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- W2088573799 abstract "All of the Group 5 anions [MOF5]2- (M = V, Nb, Ta) show the metal distorted from the center of the octahedron to the corner defined by the oxide ion. While [NbOF5]2- and [TaOF5]2- direct coordination through the oxide and trans fluoride ligands, the increase in vanadium oxide bond valence results in coordination through cis fluoride ligands in [VOF5]2-. The structure-directing properties of [VOF5]2- more closely resemble those of the Group 6 anion [MoO2F4]2-." @default.
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- W2088573799 date "2000-08-16" @default.
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- W2088573799 title "The Structure-Directing Properties of [VOF<sub>5</sub>]<sup>2</sup><sup>-</sup>" @default.
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- W2088573799 doi "https://doi.org/10.1021/ic000416d" @default.
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