Matches in SemOpenAlex for { <https://semopenalex.org/work/W2088598225> ?p ?o ?g. }
- W2088598225 endingPage "1435" @default.
- W2088598225 startingPage "1426" @default.
- W2088598225 abstract "Molar conductivities, Λ, of dilute solutions of the ionic liquids (ILs) 1-ethyl-3-methylimidazolium tetrafluoroborate ([emim][BF4]), 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]), 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), 1-hexyl-3-methylimidazolium tetrafluoroborate ([hmim][BF4]), and 1-hexyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ([hmim][NTf2]) in acetonitrile (AN) were determined as a function of temperature in the range 273.15–313.15 K. The data were analyzed with Barthel’s lcCM model to obtain limiting molar conductivities, Λ∞(T), and association constants, KA°(T) of these electrolytes. The temperature dependence of these parameters, as well as the extracted limiting cation conductivities, λi∞, were discussed. Additionally, dielectric spectra for [hmim][NTf2] + AN were analyzed in terms of ion association and ion solvation and compared with the inference from conductivity. It appears that in dilute solutions the imidazolium ring of the cations is solvated by ∼6 AN molecules that are slowed by a factor of ∼8–10 compared to the bulk-solvent dynamics. Ion association of imidazolium ILs to contact ion pairs is only moderate, similar to common 1:1 electrolytes in this solvent." @default.
- W2088598225 created "2016-06-24" @default.
- W2088598225 creator A5020331552 @default.
- W2088598225 creator A5050989717 @default.
- W2088598225 creator A5067099296 @default.
- W2088598225 date "2014-01-24" @default.
- W2088598225 modified "2023-10-09" @default.
- W2088598225 title "Ion Association of Imidazolium Ionic Liquids in Acetonitrile" @default.
- W2088598225 cites W1520716042 @default.
- W2088598225 cites W1970150223 @default.
- W2088598225 cites W1971684344 @default.
- W2088598225 cites W1974558433 @default.
- W2088598225 cites W1974873169 @default.
- W2088598225 cites W1977819335 @default.
- W2088598225 cites W1981996091 @default.
- W2088598225 cites W1993293710 @default.
- W2088598225 cites W2004612046 @default.
- W2088598225 cites W2015331718 @default.
- W2088598225 cites W2015544621 @default.
- W2088598225 cites W2020959202 @default.
- W2088598225 cites W2023234296 @default.
- W2088598225 cites W2027359281 @default.
- W2088598225 cites W2030193048 @default.
- W2088598225 cites W2032325722 @default.
- W2088598225 cites W2032592419 @default.
- W2088598225 cites W2033034994 @default.
- W2088598225 cites W2039565547 @default.
- W2088598225 cites W2040580919 @default.
- W2088598225 cites W2049073864 @default.
- W2088598225 cites W2065024506 @default.
- W2088598225 cites W2072486115 @default.
- W2088598225 cites W2074593941 @default.
- W2088598225 cites W2076240952 @default.
- W2088598225 cites W2077400462 @default.
- W2088598225 cites W2077510880 @default.
- W2088598225 cites W2082622481 @default.
- W2088598225 cites W2088624569 @default.
- W2088598225 cites W2089398473 @default.
- W2088598225 cites W2089768711 @default.
- W2088598225 cites W2090167324 @default.
- W2088598225 cites W2094106578 @default.
- W2088598225 cites W2111115175 @default.
- W2088598225 cites W2120773440 @default.
- W2088598225 cites W2130543047 @default.
- W2088598225 cites W2156206273 @default.
- W2088598225 cites W2159994653 @default.
- W2088598225 cites W2162346758 @default.
- W2088598225 cites W2165940405 @default.
- W2088598225 cites W2332982606 @default.
- W2088598225 cites W2335490489 @default.
- W2088598225 cites W4211250518 @default.
- W2088598225 cites W4230257048 @default.
- W2088598225 doi "https://doi.org/10.1021/jp412344a" @default.
- W2088598225 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24428618" @default.
- W2088598225 hasPublicationYear "2014" @default.
- W2088598225 type Work @default.
- W2088598225 sameAs 2088598225 @default.
- W2088598225 citedByCount "50" @default.
- W2088598225 countsByYear W20885982252015 @default.
- W2088598225 countsByYear W20885982252016 @default.
- W2088598225 countsByYear W20885982252017 @default.
- W2088598225 countsByYear W20885982252018 @default.
- W2088598225 countsByYear W20885982252019 @default.
- W2088598225 countsByYear W20885982252020 @default.
- W2088598225 countsByYear W20885982252021 @default.
- W2088598225 countsByYear W20885982252022 @default.
- W2088598225 countsByYear W20885982252023 @default.
- W2088598225 crossrefType "journal-article" @default.
- W2088598225 hasAuthorship W2088598225A5020331552 @default.
- W2088598225 hasAuthorship W2088598225A5050989717 @default.
- W2088598225 hasAuthorship W2088598225A5067099296 @default.
- W2088598225 hasConcept C131540310 @default.
- W2088598225 hasConcept C136957603 @default.
- W2088598225 hasConcept C145148216 @default.
- W2088598225 hasConcept C147789679 @default.
- W2088598225 hasConcept C148093993 @default.
- W2088598225 hasConcept C154881586 @default.
- W2088598225 hasConcept C161790260 @default.
- W2088598225 hasConcept C17525397 @default.
- W2088598225 hasConcept C178790620 @default.
- W2088598225 hasConcept C179104552 @default.
- W2088598225 hasConcept C181263256 @default.
- W2088598225 hasConcept C185592680 @default.
- W2088598225 hasConcept C2777463227 @default.
- W2088598225 hasConcept C2777598222 @default.
- W2088598225 hasConcept C2780471494 @default.
- W2088598225 hasConcept C2780872544 @default.
- W2088598225 hasConcept C68801617 @default.
- W2088598225 hasConceptScore W2088598225C131540310 @default.
- W2088598225 hasConceptScore W2088598225C136957603 @default.
- W2088598225 hasConceptScore W2088598225C145148216 @default.
- W2088598225 hasConceptScore W2088598225C147789679 @default.
- W2088598225 hasConceptScore W2088598225C148093993 @default.
- W2088598225 hasConceptScore W2088598225C154881586 @default.
- W2088598225 hasConceptScore W2088598225C161790260 @default.
- W2088598225 hasConceptScore W2088598225C17525397 @default.
- W2088598225 hasConceptScore W2088598225C178790620 @default.
- W2088598225 hasConceptScore W2088598225C179104552 @default.