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- W2088601013 abstract "The self-assembly of tetrathiotungstate(VI), silver sulfide and ytterbium(III) nitrate in hexamethylphosphoramide (hmp) resulted in a one-dimensional anionic W/S/Ag polymer, {[Yb(NO3)2(C6H18N3OP)4][WAgS4]}n. The central Yb coordination polyhedron in the cationic complex [Yb(hmp)4(NO3)2]+ is a distorted square antiprism. The [YbO8] assembly has an approximate fourfold inversion axis along the bisector of one of the chelating nitrate groups. The polymeric anion {[WS4Ag]−}n presents a distorted linear configuration, with W—Ag—W and Ag—W—Ag angles of 160.81 (7) and 153.41 (7)°, deviating significantly from the ideal 180°. The anionic chains in the title compound are similar to those in {N(C6H5CH2)(C2H5)3[MoS4Ag]}n: they both have a similar wave-like appearance but have different orientations. The former propagate along the c axis, while the latter have two orientations: one parallel to the a axis and the other parallel to the b axis." @default.
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- W2088601013 date "2007-07-05" @default.
- W2088601013 modified "2023-09-27" @default.
- W2088601013 title "<i>catena</i>-Poly[[tetrakis(hexamethylphosphoramide-κ<i>O</i>)bis(nitrato- κ<sup>2</sup><i>O</i>,<i>O</i>′)ytterbium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)(<i>Ag</i>—<i>W</i>)-di-μ-sulfido]]" @default.
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- W2088601013 doi "https://doi.org/10.1107/s1600536807031480" @default.
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