Matches in SemOpenAlex for { <https://semopenalex.org/work/W2088604076> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2088604076 endingPage "158" @default.
- W2088604076 startingPage "153" @default.
- W2088604076 abstract "Abstract Cavity Fourier-transform microwave spectroscopy has been used to characterise a gas phase, polar dimer of N 2 O. The polar (N 2 O) 2 unit is generated by co-expansion of a gas sample containing a small percentage of N 2 O in helium backing gas. Transitions in the pure rotational spectra of ( 15 N 2 O) 2 , ( 14 N 15 NO)( 15 N 2 O), ( 14 N 2 O)( 15 N 2 O) and ( 14 N 2 O) 2 are reported. The measured transitions of ( 15 N 2 O) 2 and ( 14 N 15 NO)( 15 N 2 O) are assigned and fitted to Hamiltonians allowing rotational, centrifugal distortion and 14 N nuclear quadrupole coupling constants to be determined. Hyperfine structure is assigned for a single J K - 1 ′ K + 1 ′ ′ → J K - 1 ″ K + 1 ″ ″ transition of both isotopomers of ( 14 N 2 O)( 15 N 2 O). Nuclear quadrupole coupling constants, χ bb , are reported for all four 14 N nuclei. The measured χ bb are in excellent agreement with those structures predicted from the measured rotational constants. The geometry of the molecule is slipped-parallel. The separation between the central nitrogen nuclei of the monomers in the r m ( 1 ) structure is 3.570(12) A with the two N 2 O monomers, respectively, oriented 54.69(68)° and 49.85(64)° to the a -inertial axis. Simulation of hyperfine structure in the spectrum of the ( 14 N 2 O) 2 isotopomer yields good qualitative agreement with experiment." @default.
- W2088604076 created "2016-06-24" @default.
- W2088604076 creator A5009749885 @default.
- W2088604076 creator A5023136050 @default.
- W2088604076 creator A5055535795 @default.
- W2088604076 creator A5065104845 @default.
- W2088604076 date "2008-09-01" @default.
- W2088604076 modified "2023-10-16" @default.
- W2088604076 title "Microwave spectrum and structure of the polar N2O dimer" @default.
- W2088604076 cites W1603209234 @default.
- W2088604076 cites W1856855022 @default.
- W2088604076 cites W1963486098 @default.
- W2088604076 cites W1983640679 @default.
- W2088604076 cites W1983652192 @default.
- W2088604076 cites W1986033601 @default.
- W2088604076 cites W1991055247 @default.
- W2088604076 cites W1992685098 @default.
- W2088604076 cites W1995509092 @default.
- W2088604076 cites W1997281437 @default.
- W2088604076 cites W1999437007 @default.
- W2088604076 cites W2005316018 @default.
- W2088604076 cites W2007698700 @default.
- W2088604076 cites W2008450431 @default.
- W2088604076 cites W2013284989 @default.
- W2088604076 cites W2016701061 @default.
- W2088604076 cites W2017547247 @default.
- W2088604076 cites W2019262080 @default.
- W2088604076 cites W2042071116 @default.
- W2088604076 cites W2043271945 @default.
- W2088604076 cites W2043735604 @default.
- W2088604076 cites W2048396141 @default.
- W2088604076 cites W2060783741 @default.
- W2088604076 cites W2066194202 @default.
- W2088604076 cites W2067221464 @default.
- W2088604076 cites W2069723789 @default.
- W2088604076 cites W2082307980 @default.
- W2088604076 cites W2089526967 @default.
- W2088604076 cites W2091411712 @default.
- W2088604076 cites W2091808076 @default.
- W2088604076 doi "https://doi.org/10.1016/j.jms.2008.02.015" @default.
- W2088604076 hasPublicationYear "2008" @default.
- W2088604076 type Work @default.
- W2088604076 sameAs 2088604076 @default.
- W2088604076 citedByCount "24" @default.
- W2088604076 countsByYear W20886040762012 @default.
- W2088604076 countsByYear W20886040762013 @default.
- W2088604076 countsByYear W20886040762014 @default.
- W2088604076 countsByYear W20886040762015 @default.
- W2088604076 countsByYear W20886040762017 @default.
- W2088604076 countsByYear W20886040762018 @default.
- W2088604076 countsByYear W20886040762021 @default.
- W2088604076 crossrefType "journal-article" @default.
- W2088604076 hasAuthorship W2088604076A5009749885 @default.
- W2088604076 hasAuthorship W2088604076A5023136050 @default.
- W2088604076 hasAuthorship W2088604076A5055535795 @default.
- W2088604076 hasAuthorship W2088604076A5065104845 @default.
- W2088604076 hasConcept C121332964 @default.
- W2088604076 hasConcept C156778621 @default.
- W2088604076 hasConcept C192562407 @default.
- W2088604076 hasConcept C2779546866 @default.
- W2088604076 hasConcept C29705727 @default.
- W2088604076 hasConcept C44838205 @default.
- W2088604076 hasConcept C46141821 @default.
- W2088604076 hasConcept C62520636 @default.
- W2088604076 hasConceptScore W2088604076C121332964 @default.
- W2088604076 hasConceptScore W2088604076C156778621 @default.
- W2088604076 hasConceptScore W2088604076C192562407 @default.
- W2088604076 hasConceptScore W2088604076C2779546866 @default.
- W2088604076 hasConceptScore W2088604076C29705727 @default.
- W2088604076 hasConceptScore W2088604076C44838205 @default.
- W2088604076 hasConceptScore W2088604076C46141821 @default.
- W2088604076 hasConceptScore W2088604076C62520636 @default.
- W2088604076 hasIssue "1-2" @default.
- W2088604076 hasLocation W20886040761 @default.
- W2088604076 hasOpenAccess W2088604076 @default.
- W2088604076 hasPrimaryLocation W20886040761 @default.
- W2088604076 hasRelatedWork W2004955289 @default.
- W2088604076 hasRelatedWork W2039192440 @default.
- W2088604076 hasRelatedWork W2039460908 @default.
- W2088604076 hasRelatedWork W2080838405 @default.
- W2088604076 hasRelatedWork W2138999454 @default.
- W2088604076 hasRelatedWork W2153560918 @default.
- W2088604076 hasRelatedWork W2323136491 @default.
- W2088604076 hasRelatedWork W2342796830 @default.
- W2088604076 hasRelatedWork W2387986268 @default.
- W2088604076 hasRelatedWork W3173685662 @default.
- W2088604076 hasVolume "251" @default.
- W2088604076 isParatext "false" @default.
- W2088604076 isRetracted "false" @default.
- W2088604076 magId "2088604076" @default.
- W2088604076 workType "article" @default.