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- W2088608669 abstract "A straightforward method of synthesising Au@Pd core–shell particles on a well characterised γ-Fe2O3 (0001) substrate has been developed which will enable fundamental studies into the surface chemistry of these catalytically interesting systems. Au and Pd were sequentially deposited onto a γ-Fe2O3 (0001) substrate in ultra high vacuum by metal vapour deposition and probed by LEIS and STM. Deposition of Au followed by heating at 573 K formed nanoparticles of 5 to 10 nm in diameter whereas subsequent deposition of Pd produced smaller nanoparticles of 2 to 4 nm diameter. At this stage, LEIS shows both metals to be present but heating the combined system to 573 K resulted in the loss of the Au signal in the LEIS and disappearance of the smaller particles from the STM images indicating the formation of Au@Pd core–shell structures." @default.
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- W2088608669 date "2013-01-01" @default.
- W2088608669 modified "2023-10-16" @default.
- W2088608669 title "A facile route to model catalysts: the synthesis of Au@Pd core–shell nanoparticles on γ-Fe2O3 (0001)" @default.
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- W2088608669 doi "https://doi.org/10.1039/c3nr03047d" @default.
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