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- W2088616650 abstract "Abstract Far-infrared absorption spectra in the submillimeter region were observed at about 2°K on some halogen complexes of protoporphyrin (Fe3+) and tetraphenylporphyrin (Fe3+) using in Michelson interferometer. The D values in the spin Hamiltonian H = D [S Z 2 − 1 3 S(S+1)] which describes the ground sextet of the 3d electrons in the Fe3+ were determined directly from these spectra. The obtained D values showed a tendency to increase with increasing atomic weight of axial ligands (halogen ions). The D values also affected by the porphyrin skeletons." @default.
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- W2088616650 date "1971-03-01" @default.
- W2088616650 modified "2023-09-26" @default.
- W2088616650 title "Far-infrared studies on hemin and hemin-like complexes" @default.
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- W2088616650 doi "https://doi.org/10.1016/0304-4165(71)90176-0" @default.
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