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- W2088640391 abstract "Es werden vier H2O-Oberschwingungen bis in überkritische Bereiche quantitativ aufgenommen. Mit Hilfe einiger Näherungsannahmen wird versucht, den Anteil an freien OH-Gruppen im H2O als Funktion der Temperatur zu bestimmen. Mit diesem Ergebnis wird ein stark vereinfachtes Clustermodell für H2O diskutiert. Nach diesem ist in der Nähe des Schmelzpunktes mit Ausdehnungen der H-Brückensysteme bis zu einigen Hundert Molekeln zu rechnen. Four overtone vibrations of H2O are measured quantitatively up to hypercritical regions. With the assumption of some approximations an attempt is made to determine the proportion of free OH groups in H2O as a function of temperature. This result is used in a discussion of a very simplified cluster model for H2O, according to which the extent of the H-bridge system in the vicinity of the melting point amounts to several hundred molecules." @default.
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- W2088640391 date "1965-09-01" @default.
- W2088640391 modified "2023-09-27" @default.
- W2088640391 title "Zur Assoziation des Wassers III. Die Temperaturabhängigkeit der Wasserbanden bis zum kritischen Punkt" @default.
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- W2088640391 doi "https://doi.org/10.1002/bbpc.19650690715" @default.
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