FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2088659153> ?p ?o ?g. }

• W2088659153 endingPage "916" @default.
• W2088659153 startingPage "908" @default.
• W2088659153 abstract "We present the analysis of the catalytic activity of gold nanoparticles in aqueous solution as a function of temperature. As a model reaction, the reduction of p-nitrophenol (Nip) by sodium borohydride (BH4–) is used. The gold nanoparticles are immobilized on cationic spherical polyelectrolyte brushes that ensure their stability against aggregation. High-resolution transmission electron microscopy shows that the Au nanoparticles are faceted nanocrystals. The average size of the nanoparticles is 2.2 nm, and the total surface area of all nanoparticles could be determined precisely and was used in the subsequent kinetic analysis. Kinetic data have been obtained between 10 and 30 °C by monitoring the concentrations of Nip and BH4– by UV–vis spectroscopy. The reaction starts after an induction time t0, and the subsequent stationary phase yields the apparent reaction rate, kapp. All kinetic data could be modeled in terms of the Langmuir–Hinshelwood model; that is, both reactants must be adsorbed onto the surface to react. The analysis of the temperature dependence of kapp leads to the heat of adsorption of both Nip and BH4– and the surface of the Au nanoparticles. Moreover, the true activation energy of the surface reaction is obtained. The analysis of t0 reveals clearly that the induction period is not related to the limitations due to diffusion but to the surface restructuring of the Au nanoparticles induced by the adsorbed Nip. The rate 1/t0 of this substrate-induced surface restructuring is found to be proportional to the square of the surface coverage, θNip, by Nip and therefore points to a cooperative process." @default.
• W2088659153 created "2016-06-24" @default.
• W2088659153 creator A5035278528 @default.
• W2088659153 creator A5060611540 @default.
• W2088659153 creator A5066696423 @default.
• W2088659153 creator A5079891754 @default.
• W2088659153 date "2011-06-28" @default.
• W2088659153 modified "2023-10-09" @default.
• W2088659153 title "Catalytic Activity of Faceted Gold Nanoparticles Studied by a Model Reaction: Evidence for Substrate-Induced Surface Restructuring" @default.
• W2088659153 cites W1963885029 @default.
• W2088659153 cites W1966876812 @default.
• W2088659153 cites W1970013931 @default.
• W2088659153 cites W1974353039 @default.
• W2088659153 cites W1974636056 @default.
• W2088659153 cites W1975795245 @default.
• W2088659153 cites W1978267907 @default.
• W2088659153 cites W1979017946 @default.
• W2088659153 cites W1979023971 @default.
• W2088659153 cites W1980412838 @default.
• W2088659153 cites W1981921119 @default.
• W2088659153 cites W1983663227 @default.
• W2088659153 cites W1983708280 @default.
• W2088659153 cites W1983814742 @default.
• W2088659153 cites W1987305605 @default.
• W2088659153 cites W1987726875 @default.
• W2088659153 cites W1988291528 @default.
• W2088659153 cites W1989282685 @default.
• W2088659153 cites W1992083269 @default.
• W2088659153 cites W1992828658 @default.
• W2088659153 cites W1993669208 @default.
• W2088659153 cites W1997573253 @default.
• W2088659153 cites W2008164657 @default.
• W2088659153 cites W2008593476 @default.
• W2088659153 cites W2009333037 @default.
• W2088659153 cites W2010762542 @default.
• W2088659153 cites W2013004437 @default.
• W2088659153 cites W2015285224 @default.
• W2088659153 cites W2017163772 @default.
• W2088659153 cites W2022006299 @default.
• W2088659153 cites W2022228194 @default.
• W2088659153 cites W2025606037 @default.
• W2088659153 cites W2028513182 @default.
• W2088659153 cites W2033755052 @default.
• W2088659153 cites W2037587948 @default.
• W2088659153 cites W2042656453 @default.
• W2088659153 cites W2042843918 @default.
• W2088659153 cites W2044433722 @default.
• W2088659153 cites W2053050719 @default.
• W2088659153 cites W2055351308 @default.
• W2088659153 cites W2056183253 @default.
• W2088659153 cites W2057663651 @default.
• W2088659153 cites W2061266901 @default.
• W2088659153 cites W2064892351 @default.
• W2088659153 cites W2066738777 @default.
• W2088659153 cites W2071330445 @default.
• W2088659153 cites W2074035298 @default.
• W2088659153 cites W2074462067 @default.
• W2088659153 cites W2077037861 @default.
• W2088659153 cites W2081656690 @default.
• W2088659153 cites W2086163572 @default.
• W2088659153 cites W2095261327 @default.
• W2088659153 cites W2106125134 @default.
• W2088659153 cites W2131805585 @default.
• W2088659153 cites W2149262099 @default.
• W2088659153 cites W2159356334 @default.
• W2088659153 cites W2314213609 @default.
• W2088659153 cites W2329207846 @default.
• W2088659153 cites W2331675907 @default.
• W2088659153 cites W2333432721 @default.
• W2088659153 cites W2951306555 @default.
• W2088659153 cites W3098686928 @default.
• W2088659153 cites W382211525 @default.
• W2088659153 cites W4211044815 @default.
• W2088659153 doi "https://doi.org/10.1021/cs200208a" @default.
• W2088659153 hasPublicationYear "2011" @default.
• W2088659153 type Work @default.
• W2088659153 sameAs 2088659153 @default.
• W2088659153 citedByCount "482" @default.
• W2088659153 countsByYear W20886591532012 @default.
• W2088659153 countsByYear W20886591532013 @default.
• W2088659153 countsByYear W20886591532014 @default.
• W2088659153 countsByYear W20886591532015 @default.
• W2088659153 countsByYear W20886591532016 @default.
• W2088659153 countsByYear W20886591532017 @default.
• W2088659153 countsByYear W20886591532018 @default.
• W2088659153 countsByYear W20886591532019 @default.
• W2088659153 countsByYear W20886591532020 @default.
• W2088659153 countsByYear W20886591532021 @default.
• W2088659153 countsByYear W20886591532022 @default.
• W2088659153 countsByYear W20886591532023 @default.
• W2088659153 crossrefType "journal-article" @default.
• W2088659153 hasAuthorship W2088659153A5035278528 @default.
• W2088659153 hasAuthorship W2088659153A5060611540 @default.
• W2088659153 hasAuthorship W2088659153A5066696423 @default.
• W2088659153 hasAuthorship W2088659153A5079891754 @default.
• W2088659153 hasConcept C104819515 @default.
• W2088659153 hasConcept C111368507 @default.
• W2088659153 hasConcept C113196181 @default.

• next