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• W2088685702 abstract "2′,3′-O-Isopropylideneguanosine derivatives 1a–c having a bulky alkylsilyl moiety showed excellent gelation ability in alkane solvents. IR spectra of the gel clearly showed the absence of hydrogen bonding interaction at the C(6)O position and, together with a CD study, a G–G base pair formation by double N(2)H⋯N(3) and additional N(2)H⋯O(2′) hydrogen bonds was indicated. X-ray diffraction and SEM studies of the xerogel and AFM observation of the transferred gel suggested the formation of a two-dimensional supramolecular assembly 2 nm in thickness. The G–G base pair formation is discussed in terms of the molecular packing in the two-dimensional assemblies." @default.
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• W2088685702 date "2007-07-01" @default.
• W2088685702 modified "2023-10-03" @default.
• W2088685702 title "Nucleoside-based organogelators: gelation by the G–G base pair formation of alkylsilylated guanosine derivatives" @default.
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• W2088685702 doi "https://doi.org/10.1016/j.tet.2007.02.010" @default.
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