FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2088688759> ?p ?o ?g. }

• W2088688759 endingPage "49" @default.
• W2088688759 startingPage "39" @default.
• W2088688759 abstract "The photophysical properties of four donor—acceptor biaryl derivatives substituted in the para positions by cyano and N,N′-dimethylamino groups were investigated in cyclohexane and acetonitrile solutions. The absorption and fluorescence spectra in non-polar cyclohexane were analysed in terms of geometrical restrictions to planarity resulting from the steric hindrance between the two aromatic subunits. The intramolecular charge transfer interactions lead to a large Stokes shift in polar solvents and to a large dipole moment in the fluorescent state. The transition dipole moment of the relaxed emitting state in acetonitrile, deduced from quantum yield and lifetime measurements, decreases with an increase in the initial inter-ring torsion angle. These observations have been interpreted to result from the solvent-induced increase in the charge transfer character of the fluorescent state. 4-Dimethylamino-4′-cyano-1,1′-binaphthyl exhibits dual fluorescence when excited in the second excited singlet state. The emission spectrum, intensity and decay times of the blue component of this fluorescence are not sensitive to solvent polarity, whereas the red component exhibits the same dependence on solvent polarity as the fluorescence of other biaryls. An asymmetric double-minimum S1 potential curve corresponding to cisoid and transoid conformers has been suggested to be responsible for this specific behaviour." @default.
• W2088688759 created "2016-06-24" @default.
• W2088688759 creator A5015183341 @default.
• W2088688759 creator A5027202163 @default.
• W2088688759 creator A5033857918 @default.
• W2088688759 creator A5059003251 @default.
• W2088688759 creator A5087647287 @default.
• W2088688759 date "1993-01-01" @default.
• W2088688759 modified "2023-10-01" @default.
• W2088688759 title "Intramolecular charge transfer properties in the excited state of para-disubstituted biaryls" @default.
• W2088688759 cites W1480021343 @default.
• W2088688759 cites W1643678644 @default.
• W2088688759 cites W1984510177 @default.
• W2088688759 cites W1985417371 @default.
• W2088688759 cites W1991161793 @default.
• W2088688759 cites W2000478108 @default.
• W2088688759 cites W2001768227 @default.
• W2088688759 cites W2003598892 @default.
• W2088688759 cites W2005460528 @default.
• W2088688759 cites W2012664032 @default.
• W2088688759 cites W2014138285 @default.
• W2088688759 cites W2016293814 @default.
• W2088688759 cites W2018358805 @default.
• W2088688759 cites W2039988601 @default.
• W2088688759 cites W2057514431 @default.
• W2088688759 cites W2063336280 @default.
• W2088688759 cites W2067240737 @default.
• W2088688759 cites W2071655669 @default.
• W2088688759 cites W2071995109 @default.
• W2088688759 cites W2080916848 @default.
• W2088688759 cites W2086161656 @default.
• W2088688759 cites W2087154985 @default.
• W2088688759 cites W2113473154 @default.
• W2088688759 cites W2323942962 @default.
• W2088688759 cites W2326203395 @default.
• W2088688759 cites W2951164945 @default.
• W2088688759 doi "https://doi.org/10.1016/1010-6030(93)80007-v" @default.
• W2088688759 hasPublicationYear "1993" @default.
• W2088688759 type Work @default.
• W2088688759 sameAs 2088688759 @default.
• W2088688759 citedByCount "28" @default.
• W2088688759 countsByYear W20886887592012 @default.
• W2088688759 countsByYear W20886887592013 @default.
• W2088688759 countsByYear W20886887592014 @default.
• W2088688759 countsByYear W20886887592015 @default.
• W2088688759 countsByYear W20886887592018 @default.
• W2088688759 countsByYear W20886887592023 @default.
• W2088688759 crossrefType "journal-article" @default.
• W2088688759 hasAuthorship W2088688759A5015183341 @default.
• W2088688759 hasAuthorship W2088688759A5027202163 @default.
• W2088688759 hasAuthorship W2088688759A5033857918 @default.
• W2088688759 hasAuthorship W2088688759A5059003251 @default.
• W2088688759 hasAuthorship W2088688759A5087647287 @default.
• W2088688759 hasConcept C121332964 @default.
• W2088688759 hasConcept C171001562 @default.
• W2088688759 hasConcept C173523689 @default.
• W2088688759 hasConcept C178790620 @default.
• W2088688759 hasConcept C181500209 @default.
• W2088688759 hasConcept C184779094 @default.
• W2088688759 hasConcept C185592680 @default.
• W2088688759 hasConcept C18705241 @default.
• W2088688759 hasConcept C2777463227 @default.
• W2088688759 hasConcept C2778237882 @default.
• W2088688759 hasConcept C32909587 @default.
• W2088688759 hasConcept C33062035 @default.
• W2088688759 hasConcept C62520636 @default.
• W2088688759 hasConcept C71240020 @default.
• W2088688759 hasConcept C75079739 @default.
• W2088688759 hasConcept C75473681 @default.
• W2088688759 hasConcept C80994870 @default.
• W2088688759 hasConcept C91881484 @default.
• W2088688759 hasConceptScore W2088688759C121332964 @default.
• W2088688759 hasConceptScore W2088688759C171001562 @default.
• W2088688759 hasConceptScore W2088688759C173523689 @default.
• W2088688759 hasConceptScore W2088688759C178790620 @default.
• W2088688759 hasConceptScore W2088688759C181500209 @default.
• W2088688759 hasConceptScore W2088688759C184779094 @default.
• W2088688759 hasConceptScore W2088688759C185592680 @default.
• W2088688759 hasConceptScore W2088688759C18705241 @default.
• W2088688759 hasConceptScore W2088688759C2777463227 @default.
• W2088688759 hasConceptScore W2088688759C2778237882 @default.
• W2088688759 hasConceptScore W2088688759C32909587 @default.
• W2088688759 hasConceptScore W2088688759C33062035 @default.
• W2088688759 hasConceptScore W2088688759C62520636 @default.
• W2088688759 hasConceptScore W2088688759C71240020 @default.
• W2088688759 hasConceptScore W2088688759C75079739 @default.
• W2088688759 hasConceptScore W2088688759C75473681 @default.
• W2088688759 hasConceptScore W2088688759C80994870 @default.
• W2088688759 hasConceptScore W2088688759C91881484 @default.
• W2088688759 hasIssue "1" @default.
• W2088688759 hasLocation W20886887591 @default.
• W2088688759 hasOpenAccess W2088688759 @default.
• W2088688759 hasPrimaryLocation W20886887591 @default.
• W2088688759 hasRelatedWork W1979424184 @default.
• W2088688759 hasRelatedWork W2004599238 @default.
• W2088688759 hasRelatedWork W2071379296 @default.
• W2088688759 hasRelatedWork W2104099569 @default.
• W2088688759 hasRelatedWork W2461429047 @default.

• next