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• W2088688856 startingPage "6806" @default.
• W2088688856 abstract "A series of metal complexes was synthesized in which arenes were dihapto-coordinated to π-basic metal fragments having the general form {TpM(π-acid)(L)}, where Tp = hydridotris(pyrazolyl)borate, M = rhenium, molybdenum, or tungsten, π-acid = CO or NO+, and L = 1-methylimidazole, 1-butylimidazole, pyridine, or trimethylphosphine. The arene complexes were shown to be significantly more basic than the analogous pentaammineosmium(II) arene complexes and were protonated by moderate acids to give remarkably stable η2 and η3 arenium cation complexes. A crystal structure of [TpRe(CO)(MeIm)(5,6-η2-2H-anisolium)](OTf) confirmed the η2 coordination of the anisolium ligand, but suggests a weak long-range interaction between the metal and C1 of the anisolium." @default.
• W2088688856 created "2016-06-24" @default.
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• W2088688856 date "2004-05-07" @default.
• W2088688856 modified "2023-10-16" @default.
• W2088688856 title "Transition Metal-Stabilized Arenium Cations: Protonation of Arenes Dihapto-Coordinated to π-Basic Metal Fragments" @default.
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• W2088688856 doi "https://doi.org/10.1021/ja039824h" @default.
• W2088688856 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15161309" @default.
• W2088688856 hasPublicationYear "2004" @default.
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