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- W2088700862 abstract "Abstract Fifteen tetrakis chelate salts of structure Q + [(BTF) 4 Eu] − , where Q + is an organic cation, have been prepared from the β-diketone benzoyltrifluoroacetone (HBTF); and their properties have been compared with those of the corresponding tris chelate (BTF) 3 Eu·2H 2 O. The fluorescence properties of the tetrakis chelates in the solid state are dependent, to a significant extent, on the nature of the cation. In acetonitrile solution the tetrakis salts are largely dissociated to Q + and [(BTF) 4 Eu] − . The observed solution fluorescence, due to [(BTF) 4 Eu] − is independent of the cation except in those instances (pyridinium, quinolinium, and iso quinolinium) where there is interaction between anion and cation to give equilibrium concentrations of (BTF) 3 Eu. The tetrakis salts show stronger europium fluorescence than does the tris chelate, both as solids and in solution. The thermal properties of the solid compounds are discussed." @default.
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- W2088700862 title "Properties of some europium laser chelates derived from benzoyltrifluoroacetone" @default.
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- W2088700862 doi "https://doi.org/10.1016/0022-1902(66)80028-3" @default.
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