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- W2088751005 abstract "EPR has been performed on single crystals of nominally pure 7Li2O: (a) as grown, (b) after X-irradiation, and (c) after subsequent annealing: (a) shows evidence of several sites of Fe3+ in low abundance; (b) shows additional spectra from an electron centre with g=2.003(1), associated with a brown coloration of the crystal, and also from Fe3+ at tetragonal sites; (c) shows that the electron centre (and the coloration) has been destroyed and the tetragonal Fe3+ concentration has been greatly enhanced. The fine structure parameters of the tetragonal Fe3+ centres, b20=-0.1445(5) cm-1, b40=-27(3)*10-4 cm-1 and b44=-90(2)*10-4 cm-1, are shown to be well described by the Newman superposition model, using a structural model for the centre comprising Fe3+ substituting for Li+ and two adjacent Li+ vacancies. Models are proposed for the changes that occur in this material on X-irradiation and annealing." @default.
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- W2088751005 date "1991-10-28" @default.
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- W2088751005 title "Electron magnetic resonance in lithium oxide from a centre containing Fe3+" @default.
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