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- W2088794018 endingPage "1072" @default.
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- W2088794018 abstract "A new unsymmetrical photochromic diarylethene, 1-(2-methyl-5-phenyl-3-thienyl)-2-[2-methyl-5-(3-trifluoromethylphenyl)-3-thienyl]perfluorocyclopentene (1a), was synthesized and its structure was determined by single-crystal X-ray diffraction analysis. Its optical and electrochemical properties, including photochromic reactivity both in solution and in the solid state (PMMA film and the single-crystalline phase), fluorescence and electrochemical properties were investigated in detail. The compound showed excellent photochromism even in the single-crystalline phase by photo-irradiation. In acetonitrile, the open-ring isomer of diarylethene 1 exhibited relatively strong fluorescence at 470 nm when excited at 300 nm, and its emission intensity decreased along with the photochromism upon irradiation with 313 nm light. Its closed-ring isomer showed almost no fluorescence. The electrochemical properties of diarylethene were investigated by performing cyclic voltammetry experiment and its HOMO and LUMO energy level were calculated." @default.
- W2088794018 created "2016-06-24" @default.
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- W2088794018 date "2008-10-01" @default.
- W2088794018 modified "2023-10-18" @default.
- W2088794018 title "Synthesis, crystal structure and optoelectronic properties of a new unsymmetrical photochromic diarylethene" @default.
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- W2088794018 doi "https://doi.org/10.1016/j.saa.2007.10.026" @default.
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