Matches in SemOpenAlex for { <https://semopenalex.org/work/W2088798384> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2088798384 endingPage "4213" @default.
- W2088798384 startingPage "4210" @default.
- W2088798384 abstract "Solid pure osmium phthalocyanine, as obtained from its adduct [PcOs(py)(2)], is an air-stable solid amorphous material. Its structure has been examined by the wide-angle X-ray scattering (WAXS) technique. Experimental data are best fitted by assuming the molecule to consist of a dimeric unit, (PcOs)(2), held together by a direct metal-metal linkage. The short Os-Os distance (2.38(1) Å) is consistent with the presence of a double bond between the two Os(II) atoms. Each Pc skeleton has a domed conformation with displacement of the respective Os atom from the plane of the four coordinating nitrogen atoms (0.40 Å) toward the other Os atom. The solid-state structure consists of disordered couples of parallel chains of (PcOs)(2). On average, six dimeric units are aligned along the stacking direction within each chain. The relative orientation of the two intradimer Pc units is 30 degrees, eclipsing occurring for the interdimer adjacent Pc units along the chain. Magnetic susceptibility measurements in the temperature range 5-300 K indicate a strong spin-spin coupling for the two metal centers in the dimer and suggest an electronic energy level sequence sigma(2)pi(4)delta(2)delta(2)pi(2) and a nonmagnetic ground state for the complex. Room-temperature electrical conductivity measurements show a sigma(RT) value of 1 x 10(-)(5) Omega(-)(1) cm(-)(1)." @default.
- W2088798384 created "2016-06-24" @default.
- W2088798384 creator A5008615163 @default.
- W2088798384 creator A5023481017 @default.
- W2088798384 creator A5024450493 @default.
- W2088798384 creator A5049378192 @default.
- W2088798384 date "1998-08-01" @default.
- W2088798384 modified "2023-09-27" @default.
- W2088798384 title "Dimeric Osmium Phthalocyanine Organized in Discrete Columnarly Stacked Assemblies: Structure, Magnetism, and Electrical Conductivity Properties" @default.
- W2088798384 cites W1981916259 @default.
- W2088798384 cites W1988906372 @default.
- W2088798384 cites W2055429896 @default.
- W2088798384 cites W2061814366 @default.
- W2088798384 cites W2061858561 @default.
- W2088798384 cites W2062224143 @default.
- W2088798384 cites W2065670567 @default.
- W2088798384 cites W2070200949 @default.
- W2088798384 cites W2087016059 @default.
- W2088798384 cites W2090442823 @default.
- W2088798384 cites W2145755838 @default.
- W2088798384 cites W2149319894 @default.
- W2088798384 cites W2041549115 @default.
- W2088798384 doi "https://doi.org/10.1021/ic980202k" @default.
- W2088798384 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11670553" @default.
- W2088798384 hasPublicationYear "1998" @default.
- W2088798384 type Work @default.
- W2088798384 sameAs 2088798384 @default.
- W2088798384 citedByCount "13" @default.
- W2088798384 countsByYear W20887983842017 @default.
- W2088798384 crossrefType "journal-article" @default.
- W2088798384 hasAuthorship W2088798384A5008615163 @default.
- W2088798384 hasAuthorship W2088798384A5023481017 @default.
- W2088798384 hasAuthorship W2088798384A5024450493 @default.
- W2088798384 hasAuthorship W2088798384A5049378192 @default.
- W2088798384 hasConcept C115624301 @default.
- W2088798384 hasConcept C149635348 @default.
- W2088798384 hasConcept C161790260 @default.
- W2088798384 hasConcept C16889073 @default.
- W2088798384 hasConcept C178790620 @default.
- W2088798384 hasConcept C185592680 @default.
- W2088798384 hasConcept C198819137 @default.
- W2088798384 hasConcept C2779546866 @default.
- W2088798384 hasConcept C2780761128 @default.
- W2088798384 hasConcept C33347731 @default.
- W2088798384 hasConcept C41008148 @default.
- W2088798384 hasConcept C540285154 @default.
- W2088798384 hasConcept C544153396 @default.
- W2088798384 hasConcept C55493867 @default.
- W2088798384 hasConcept C555196967 @default.
- W2088798384 hasConcept C58312451 @default.
- W2088798384 hasConcept C8010536 @default.
- W2088798384 hasConceptScore W2088798384C115624301 @default.
- W2088798384 hasConceptScore W2088798384C149635348 @default.
- W2088798384 hasConceptScore W2088798384C161790260 @default.
- W2088798384 hasConceptScore W2088798384C16889073 @default.
- W2088798384 hasConceptScore W2088798384C178790620 @default.
- W2088798384 hasConceptScore W2088798384C185592680 @default.
- W2088798384 hasConceptScore W2088798384C198819137 @default.
- W2088798384 hasConceptScore W2088798384C2779546866 @default.
- W2088798384 hasConceptScore W2088798384C2780761128 @default.
- W2088798384 hasConceptScore W2088798384C33347731 @default.
- W2088798384 hasConceptScore W2088798384C41008148 @default.
- W2088798384 hasConceptScore W2088798384C540285154 @default.
- W2088798384 hasConceptScore W2088798384C544153396 @default.
- W2088798384 hasConceptScore W2088798384C55493867 @default.
- W2088798384 hasConceptScore W2088798384C555196967 @default.
- W2088798384 hasConceptScore W2088798384C58312451 @default.
- W2088798384 hasConceptScore W2088798384C8010536 @default.
- W2088798384 hasIssue "17" @default.
- W2088798384 hasLocation W20887983841 @default.
- W2088798384 hasLocation W20887983842 @default.
- W2088798384 hasOpenAccess W2088798384 @default.
- W2088798384 hasPrimaryLocation W20887983841 @default.
- W2088798384 hasRelatedWork W1984807283 @default.
- W2088798384 hasRelatedWork W2022850821 @default.
- W2088798384 hasRelatedWork W2036716385 @default.
- W2088798384 hasRelatedWork W2038376715 @default.
- W2088798384 hasRelatedWork W2050775256 @default.
- W2088798384 hasRelatedWork W2065487482 @default.
- W2088798384 hasRelatedWork W2074862782 @default.
- W2088798384 hasRelatedWork W2087665121 @default.
- W2088798384 hasRelatedWork W2321265370 @default.
- W2088798384 hasRelatedWork W4223940711 @default.
- W2088798384 hasVolume "37" @default.
- W2088798384 isParatext "false" @default.
- W2088798384 isRetracted "false" @default.
- W2088798384 magId "2088798384" @default.
- W2088798384 workType "article" @default.