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- W2088798713 abstract "Reaction of the dipotassium salt of the dipyrrolide dianion [1,1-(2-C4H3N)2C6H10]2- with FeCl2(THF)1.5 afforded the tetranuclear [μ,η5-{[1,1-(2-C4H3N)2C6H10]2Fe}Fe]2 (1) cluster containing two diamagnetic ferrous links π-bonded to two pyrrolyl rings of two ligands and closely reminiscent of a ferrocenoid-type arrangement. Reaction of the dianionic metalate {[[1,1-(2-C4H3N)2C6H10]2Co][K(THF)]2}n with FeCl2(THF)1.5 also afforded the corresponding [μ,η5-{[1,1-(2-C4H3N)2C6H10]2Co}Fe]2 nearly isostructural with 1. This indicates that the two ferrous links provide the driving force for assembling the two clusters, although the two structures are labile and may be disrupted by simple treatment with pyridine." @default.
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- W2088798713 date "2003-04-22" @default.
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- W2088798713 title "Labile Tetranuclear Fe(II) and Co(II) Clusters of a Dipyrrolide Dianion with Two Diamagnetic Ferrous Links" @default.
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- W2088798713 doi "https://doi.org/10.1021/om030111h" @default.
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