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• W2088819224 endingPage "838" @default.
• W2088819224 startingPage "831" @default.
• W2088819224 abstract "A borondipyrromethene-based Zn2+ fluorescent probe BODPAQ was designed and synthesized. The chelators in BODPAQ, 2,2′-dipicolylamine (DPA) and 8-aminoquinoline (AQ), coordinate to Zn2+ in a synergic manner. As a result, BODPAQ displays high Zn2+ selectivity with a dramatic enhanced emission accompanied by a notable hypsochromic shift due to the binary inhibition effect of PET and ICT mechanisms, enabling the detection of Zn2+ by both ratiometric and normal turn-on fluorescence methods in acetonitrile. Interestingly, the sensitivity of BODPAQ towards Zn2+ changes upon varying the compositions of buffer solutions. In 3-morpholinopropanesulfonic acid (MOPS) buffer aqueous solution (50% CH3CN), BODPAQ displays the highest sensitivity for Zn2+, while in citrate–phosphate buffer, BODPAQ shows no response to Zn2+." @default.
• W2088819224 created "2016-06-24" @default.
• W2088819224 creator A5015628874 @default.
• W2088819224 creator A5032976671 @default.
• W2088819224 creator A5042894474 @default.
• W2088819224 creator A5087724228 @default.
• W2088819224 date "2012-01-01" @default.
• W2088819224 modified "2023-09-27" @default.
• W2088819224 title "Development of a borondipyrromethene-based Zn²⁺fluorescent probe: solvent effects on modulation sensing ability" @default.
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• W2088819224 doi "https://doi.org/10.1039/c1dt10797f" @default.
• W2088819224 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22094853" @default.
• W2088819224 hasPublicationYear "2012" @default.
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