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• W2088840611 abstract "The selective catalytic reduction reaction of nitric oxide by ammonia over vanadia-titania catalysts is one of the methods of removing NOx pollution. In the present study, it has been possible to identify the reaction mechanism and the nature of the active sites in these catalysts by combining transient or steady-state in situ (Fourier transform infrared spectroscopy) experiments directly with on-line activity studies. The results suggest a catalytic cycle that consists of both acid and redox reactions and involves both surface V—OH (Brønsted acid sites) and V=O species. A fundamental microkinetic model is proposed, which accounts for the observed industrial kinetics performance." @default.
• W2088840611 created "2016-06-24" @default.
• W2088840611 creator A5015738926 @default.
• W2088840611 date "1994-08-26" @default.
• W2088840611 modified "2023-10-11" @default.
• W2088840611 title "Mechanism of the Selective Catalytic Reduction of Nitric Oxide by Ammonia Elucidated by in Situ On-Line Fourier Transform Infrared Spectroscopy" @default.
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• W2088840611 doi "https://doi.org/10.1126/science.265.5176.1217" @default.
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