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- W2088842455 abstract "Abstract The post-deposition treatment of water-processable, polymer acid-templated conducting polymers with dichloroacetic acid has recently been shown to enhance in-plane conductivity by orders of magnitude. Here, we evaluate both the in-plane and out-of-plane conductivities of dichloroacetic acid-treated conducting polymer films, and track the accompanying evolution of film structure and composition. Films of poly(ethylene dioxythiophene)–poly(styrene sulfonic acid), PEDOT–PSS, exhibit improvements in both in-plane and out-of-plane conductivities following dichloroacetic acid treatment, associated with the removal of excess PSS from the surface. Conversely, polyaniline–poly(2-acrylamido-2-methyl-1-propanesulfonic acid), PANI–PAAMPSA, films are characterized by high anisotropies in conductivity, with the in-plane conductivity being orders of magnitude higher following DCA treatment and the out-of-plane conductivity substantially lower after the same treatment. Our experiments indicate that this unusual electrical anisotropy results from a vertically inhomogeneous composition profile." @default.
- W2088842455 created "2016-06-24" @default.
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- W2088842455 date "2014-02-01" @default.
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- W2088842455 title "Structural origin of anisotropic transport in electrically conducting dichloroacetic acid-treated polymers" @default.
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- W2088842455 doi "https://doi.org/10.1016/j.orgel.2013.12.019" @default.
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