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- W2088853424 startingPage "2683" @default.
- W2088853424 abstract "We have measured the coexistence curve of a high-molecular-weight (${M}_{w}=1.56ifmmodetimeselsetexttimesfi{}{10}^{6}$) polystyrene in cyclohexane over a temperature range of $4ifmmodetimeselsetexttimesfi{}{10}^{ensuremath{-}5}<frac{({T}_{c}ensuremath{-}T)}{{T}_{c}}<4ifmmodetimeselsetexttimesfi{}{10}^{ensuremath{-}2}$. The concentration difference ${X}^{+}ensuremath{-}{X}^{ensuremath{-}}$, in volume fraction of polystyrene, was well represented by the expression ${X}^{+}ensuremath{-}{X}^{ensuremath{-}}=B{ensuremath{epsilon}}^{ensuremath{beta}}+{B}_{1}{ensuremath{epsilon}}^{ensuremath{beta}+ensuremath{Delta}}+{B}_{2}{ensuremath{epsilon}}^{ensuremath{beta}+2ensuremath{Delta}}$ based on the Wegner expansion, where $ensuremath{beta}=0.327ifmmodepmelsetextpmfi{}0.004$ and $ensuremath{Delta}$ is fixed at 0.50. The concentration difference could also be well represented by the expression ${X}^{+}ensuremath{-}{X}^{ensuremath{-}}=B{ensuremath{epsilon}}^{ensuremath{beta}}+{B}^{ensuremath{'}}{ensuremath{epsilon}}^{{ensuremath{beta}}^{ensuremath{'}}}$, where a somewhat higher value of $ensuremath{beta}$ was required. The diameter in the temperature range $4ifmmodetimeselsetexttimesfi{}{10}^{ensuremath{-}5}<frac{({T}_{c}ensuremath{-}T)}{{T}_{c}}<{10}^{ensuremath{-}2}$ was represented by $frac{({X}^{+}+{X}^{ensuremath{-}})}{2}ensuremath{-}{X}_{c}=A{ensuremath{epsilon}}^{ensuremath{mu}}$, where $ensuremath{mu}=0.860ifmmodepmelsetextpmfi{}0.006$. We have established, for the first time, the value of the asymptotic critical exponent $ensuremath{beta}$ of even a polymer system to be like that presently calculated for the Ising model. The observed exponent $ensuremath{mu}(=1ensuremath{-}ensuremath{alpha})$ is consistent with results of specific-heat measurements." @default.
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- W2088853424 date "1978-12-01" @default.
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- W2088853424 title "Coexistence curve and diameter of polystyrene in cyclohexane" @default.
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- W2088853424 doi "https://doi.org/10.1103/physreva.18.2683" @default.
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