FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2088897692> ?p ?o ?g. }

• W2088897692 endingPage "305" @default.
• W2088897692 startingPage "296" @default.
• W2088897692 abstract "Glassy carbon (GC) surfaces modified with monolayers of biphenyl and nitrobiphenyl molecules were examined as voltammetric electrodes for ferrocene, benzoquinone, and tetracyanoquinodimethane electrochemistry in acetonitrile. The modified electrodes exhibited slower electron transfer than unmodified GC, by factors that varied with the monolayer and redox system. However, after a negative potential excursion to ∼−2.0 V versus Ag+/Ag, the modified electrodes exhibited much faster electron-transfer kinetics, approaching those observed on unmodified GC. The effect is attributed to an apparently irreversible structural change in the biphenyl or nitrobiphenyl monolayer, which increases the rate of electron tunneling. The transition to the “ON” state is associated with electron injection into the monolayer similar to that observed in previous spectroscopic investigations and causes a significant decrease in the calculated HOMO−LUMO gap for the monolayer molecule. Once the monolayer is switched ON, it supports rapid electron exchange with outer-sphere redox systems, but not with dopamine, which requires adsorption to the GC surface. The increase in electron-transfer rate with electron injection is consistent with an increase in electron tunneling rate through the monolayer, caused by a significant decrease in tunneling barrier height. The ON electrode can reduce biphenyl- or nitrobiphenyldiazonium reagent in solution to permit formation of a second modification layer of biphenyl or nitrobiphenyl molecules. This “double derivatization” procedure was used to prepare tetraphenyl- and nitrotetraphenyl-modified electrodes, which exhibit significantly slower electron transfer than their biphenyl and nitrobiphenyl counterparts. A “switching” electrode may have useful properties for electroanalytical applications and possibly in electrocatalysis. In addition, the ON state represents an “organic electrode” in which electron transfer occurs at an interface between an organic conductor and a solution rather than an interface between a solution and a metal or carbon electrode." @default.
• W2088897692 created "2016-06-24" @default.
• W2088897692 creator A5000720807 @default.
• W2088897692 creator A5007874885 @default.
• W2088897692 creator A5025019310 @default.
• W2088897692 creator A5047050944 @default.
• W2088897692 date "2002-12-12" @default.
• W2088897692 modified "2023-09-26" @default.
• W2088897692 title "Modified Carbon Surfaces as “Organic Electrodes” That Exhibit Conductance Switching" @default.
• W2088897692 cites W1967169263 @default.
• W2088897692 cites W1971041083 @default.
• W2088897692 cites W1972710779 @default.
• W2088897692 cites W1976572795 @default.
• W2088897692 cites W1978922517 @default.
• W2088897692 cites W1979776957 @default.
• W2088897692 cites W1985755232 @default.
• W2088897692 cites W1992249905 @default.
• W2088897692 cites W1992928973 @default.
• W2088897692 cites W1993365660 @default.
• W2088897692 cites W1994591490 @default.
• W2088897692 cites W1999102305 @default.
• W2088897692 cites W2003409173 @default.
• W2088897692 cites W2017021058 @default.
• W2088897692 cites W2017390794 @default.
• W2088897692 cites W2017997919 @default.
• W2088897692 cites W2018294724 @default.
• W2088897692 cites W2018610761 @default.
• W2088897692 cites W2021426946 @default.
• W2088897692 cites W2021458657 @default.
• W2088897692 cites W2022340280 @default.
• W2088897692 cites W2027327489 @default.
• W2088897692 cites W2028787256 @default.
• W2088897692 cites W2029101524 @default.
• W2088897692 cites W2030911616 @default.
• W2088897692 cites W2036465980 @default.
• W2088897692 cites W2043740740 @default.
• W2088897692 cites W2048625812 @default.
• W2088897692 cites W2065509584 @default.
• W2088897692 cites W2071602014 @default.
• W2088897692 cites W2076235405 @default.
• W2088897692 cites W2079490844 @default.
• W2088897692 cites W2083530550 @default.
• W2088897692 cites W2084708798 @default.
• W2088897692 cites W2085966381 @default.
• W2088897692 cites W2086374051 @default.
• W2088897692 cites W2089727079 @default.
• W2088897692 cites W2090920532 @default.
• W2088897692 cites W2091055006 @default.
• W2088897692 cites W2091793609 @default.
• W2088897692 cites W2100732434 @default.
• W2088897692 cites W2133899617 @default.
• W2088897692 cites W2140747378 @default.
• W2088897692 cites W2142059002 @default.
• W2088897692 cites W2172172128 @default.
• W2088897692 cites W2605365912 @default.
• W2088897692 cites W4244480240 @default.
• W2088897692 doi "https://doi.org/10.1021/ac026107h" @default.
• W2088897692 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12553765" @default.
• W2088897692 hasPublicationYear "2002" @default.
• W2088897692 type Work @default.
• W2088897692 sameAs 2088897692 @default.
• W2088897692 citedByCount "125" @default.
• W2088897692 countsByYear W20888976922012 @default.
• W2088897692 countsByYear W20888976922013 @default.
• W2088897692 countsByYear W20888976922014 @default.
• W2088897692 countsByYear W20888976922015 @default.
• W2088897692 countsByYear W20888976922016 @default.
• W2088897692 countsByYear W20888976922017 @default.
• W2088897692 countsByYear W20888976922018 @default.
• W2088897692 countsByYear W20888976922019 @default.
• W2088897692 countsByYear W20888976922020 @default.
• W2088897692 countsByYear W20888976922021 @default.
• W2088897692 countsByYear W20888976922022 @default.
• W2088897692 countsByYear W20888976922023 @default.
• W2088897692 crossrefType "journal-article" @default.
• W2088897692 hasAuthorship W2088897692A5000720807 @default.
• W2088897692 hasAuthorship W2088897692A5007874885 @default.
• W2088897692 hasAuthorship W2088897692A5025019310 @default.
• W2088897692 hasAuthorship W2088897692A5047050944 @default.
• W2088897692 hasConcept C113196181 @default.
• W2088897692 hasConcept C123669783 @default.
• W2088897692 hasConcept C14158195 @default.
• W2088897692 hasConcept C147789679 @default.
• W2088897692 hasConcept C17525397 @default.
• W2088897692 hasConcept C178790620 @default.
• W2088897692 hasConcept C185592680 @default.
• W2088897692 hasConcept C2776422427 @default.
• W2088897692 hasConcept C2777869211 @default.
• W2088897692 hasConcept C2780591471 @default.
• W2088897692 hasConcept C2780713452 @default.
• W2088897692 hasConcept C32909587 @default.
• W2088897692 hasConcept C52859227 @default.
• W2088897692 hasConcept C55493867 @default.
• W2088897692 hasConcept C7070889 @default.
• W2088897692 hasConcept C75473681 @default.
• W2088897692 hasConceptScore W2088897692C113196181 @default.
• W2088897692 hasConceptScore W2088897692C123669783 @default.
• W2088897692 hasConceptScore W2088897692C14158195 @default.

• next