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• W2088908052 abstract "Abstract Admixtures of various oxidized sterol compounds and 1-palmitoyl, 2-oleoyl phosphatidylethanolamine (POPE) in buffer, or 1,2 O-dihexadecylphosphatidylcholine (DHPC) in water were examined using real time x-ray diffraction. The formation of non-lamellar POPE phases was enhanced by the presence of 5 mole% cholesterol, 7-ketocholesterol, or 20α-hydroxycholesterol, but not by the presence of 5 mole% 5α-cholestane-3p,5,6β-triol. The presence of 5 mole% cholesterol, 7-ketocholesterol or 5α-cholestane-3β,5,6β-triol was sufficient to eliminate the DHPC interdigitated gel bilayer phase over its usual temperature range and to replace it with a gel state ripple phase. Sterol-phospholipid interactions thus resulted in a direct conversion from the sub gel bilayer phase to the gel state ripple phase for DHPC mixtures with 5 mole% cholesterol, 7-ketocholesterol, or 5α-cholestane-3β,5,6β-triol rather than the sequence of interdigitated sub gel bilayer phase to interdigitated gel state bilayer phase to a final state of gel state ripple phase observed for DHPC in water. These results can be used to interpret the extent of sterol influence on the intra-bilayer interactions between lipid molecules." @default.
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• W2088908052 date "1992-03-01" @default.
• W2088908052 modified "2023-09-27" @default.
• W2088908052 title "Modulation of Phospholipid Phase Structures and Transitions Induced by Oxysterols" @default.
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• W2088908052 doi "https://doi.org/10.1080/10587259208028732" @default.
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