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- W2088928384 abstract "The crystal and molecular structure and the absolute configuration of the title compound has been determined by X-ray diffraction methods. The crystals are orthorhombic with cell dimensions: a= 10·639 ± 0·002, b= 12·036 ± 0·004, and c= 26·979 ± 0·007 A, space group P212121, Z= 4. The structure was solved by the heavy-atom method. After refinement by least-squares methods using anisotropic thermal parameters, R was 0·072 for 2475 observed reflections. The molecule consists of two units derived from morphine and cularine, linked by a spiro-ring junction. The absolute configuration was determined and shows that the morphine-related fragment has the opposite configuration to that found in morphine." @default.
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- W2088928384 date "1972-01-01" @default.
- W2088928384 modified "2023-09-26" @default.
- W2088928384 title "Crystal structure and absolute configuration of dihydro-O-methyl-cancentrinemethine hydrobromide, a derivative of the alkaloid cancentrine" @default.
- W2088928384 doi "https://doi.org/10.1039/p29720001219" @default.
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