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• W2088930231 abstract "Thermoreversible organogels were prepared from carbamates with alkyl side chains of different lengths. Gelation was possible only up to an alkyl side chain length of 12 carbons, beyond which crystallization occurs, due to the dominant van der Waals interaction between the alkyl chains. This is in contrast to other alkane-based organogels, in which gelating efficiency increased with the length of the alkane chain (see Abdallah, D. J.; Weiss, R. G. Adv. Mater. 2000, 12, 1237). The critical concentration for gelation decreases drastically with an increase in the side chain length. Xerogels of these show birefringent fibers with uniform cross section and unlimited growth in one direction. The extent of this unlimited growth is affected by the length of the alkyl side chain in the carbamate, which finally ceases the gel formation ability of the carbamate. Cryogenic scanning electron microscopy images of the gels are similar to those of xerogels. From X-ray diffraction of the fibers, we propose that the growth direction is along the plane of hydrogen bonds between the carbamate molecules. The thickness of the fibers depends on the length of the alkyl side chain. Morphological differences are seen between gels prepared by slow cooling and quenching of the solution. Thus, the morphology of the fibrous xerogels of the carbamates can be tailored for specific applications, by the choice of the alkyl side chain length and the rate of cooling the solution." @default.
• W2088930231 created "2016-06-24" @default.
• W2088930231 creator A5049113864 @default.
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• W2088930231 date "2005-03-30" @default.
• W2088930231 modified "2023-10-11" @default.
• W2088930231 title "Low Molecular Weight Organogels Based on Long-Chain Carbamates" @default.
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• W2088930231 doi "https://doi.org/10.1021/la047449g" @default.
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