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- W2088955020 abstract "The kinetics of polymerization of acrylonitrile (AN) was carried out under heterogeneous condition using a new multi-site phase-transfer catalyst (MPTC), viz., N,N'-dihexyl-4,4'-bipyridinium dibromide in the presence of water soluble initiator, potassium peroxydisulphate (PDS) under chlorobenzene/water two phase system assisted by ultrasound irradiation at constant temperature 60+1°C under nitrogen atmosphere. The rate of polymerization increases with an increasing the concentrations of AN, MPTC and PDS. The order with respect to [AN], [MPTC], and [PDS] were found to be 1.01, 1.03 and 0.52, respectively. Based on the observed results a suitable mechanism has been proposed to account for the experimental observations followed by a discussion on its significance." @default.
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- W2088955020 date "2015-01-01" @default.
- W2088955020 modified "2023-10-16" @default.
- W2088955020 title "Effect of ultrasound in the free radical polymerization of acrylonitrile under a new multi-site phase-transfer catalyst – A kinetic study" @default.
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- W2088955020 doi "https://doi.org/10.1016/j.ultsonch.2014.05.002" @default.
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