Matches in SemOpenAlex for { <https://semopenalex.org/work/W2088965274> ?p ?o ?g. }
Showing items 1 to 80 of
80
with 100 items per page.
- W2088965274 endingPage "137" @default.
- W2088965274 startingPage "107" @default.
- W2088965274 abstract "Jonah D.A. and Cochran H.D., 1994. Chemical potentials in dilute, multicomponent solutions. Fluid Phase Equilibria, 92: 107-137. The Debenedetti-Kumar (DK) formula for solute fugacity coefficients in highly dilute binary solutions has been generalized to multicomponent mixtures with a single solvent and several solutes at high dilution. It is shown how models based on conformal solution (CS) theory or the Kirkwood-Buff (KB) solution theory or their combination may be used to investigate the cosolute effect on the solubilities of solids in supercritical (SC) fluid solvents. The generalized DK (GDK) formulae have been tested with the Peng-Robinson (PR) equation of state (EOS), by using it to compute approximate solute fugacity coefficients in dilute ternary SC solutions with two solids (solute and cosolute) at various dilutions and comparing with values based on the use of exact thermodynamic expressions with the PR EOS for fugacity coefficients in mixtures. The two sets of values are found to be in good agreement. Further tests along these lines consist of using both sets of solute fugacity coefficients in standard phase equilibrium equations to evaluate solute and cosolute mole fractions. Again, the two sets of values determined in this way show good agreement, thereby giving us grounds to suppose the GDK formulae are of sufficient accuracy to be used in the study of such mixtures. The CS model has been used in conjunction with the GDK formulae to successfully correlate several solid solubilities in SC CO2 in the presence of a cosolute. Other potential applications of the GDK formulae include modeling the solubility of gases in liquids and the solubility of solids in SC fluid solvents containing an added entrainer." @default.
- W2088965274 created "2016-06-24" @default.
- W2088965274 creator A5005494816 @default.
- W2088965274 creator A5034285618 @default.
- W2088965274 date "1994-01-01" @default.
- W2088965274 modified "2023-10-14" @default.
- W2088965274 title "Chemical potentials in dilute, multicomponent solutions" @default.
- W2088965274 cites W1628356703 @default.
- W2088965274 cites W1970973025 @default.
- W2088965274 cites W2012785183 @default.
- W2088965274 cites W2012900172 @default.
- W2088965274 cites W2014788706 @default.
- W2088965274 cites W2015772873 @default.
- W2088965274 cites W2035442056 @default.
- W2088965274 cites W2039482430 @default.
- W2088965274 cites W2043278958 @default.
- W2088965274 cites W2071697208 @default.
- W2088965274 cites W2089240919 @default.
- W2088965274 cites W2093806300 @default.
- W2088965274 cites W2094614609 @default.
- W2088965274 cites W2127458597 @default.
- W2088965274 cites W4231170041 @default.
- W2088965274 doi "https://doi.org/10.1016/0378-3812(94)80044-8" @default.
- W2088965274 hasPublicationYear "1994" @default.
- W2088965274 type Work @default.
- W2088965274 sameAs 2088965274 @default.
- W2088965274 citedByCount "13" @default.
- W2088965274 countsByYear W20889652742016 @default.
- W2088965274 countsByYear W20889652742018 @default.
- W2088965274 countsByYear W20889652742019 @default.
- W2088965274 countsByYear W20889652742023 @default.
- W2088965274 crossrefType "journal-article" @default.
- W2088965274 hasAuthorship W2088965274A5005494816 @default.
- W2088965274 hasAuthorship W2088965274A5034285618 @default.
- W2088965274 hasConcept C118419359 @default.
- W2088965274 hasConcept C121332964 @default.
- W2088965274 hasConcept C147789679 @default.
- W2088965274 hasConcept C170961132 @default.
- W2088965274 hasConcept C178790620 @default.
- W2088965274 hasConcept C184651966 @default.
- W2088965274 hasConcept C185592680 @default.
- W2088965274 hasConcept C199360897 @default.
- W2088965274 hasConcept C41008148 @default.
- W2088965274 hasConcept C64452783 @default.
- W2088965274 hasConcept C85084404 @default.
- W2088965274 hasConcept C96618451 @default.
- W2088965274 hasConcept C97355855 @default.
- W2088965274 hasConceptScore W2088965274C118419359 @default.
- W2088965274 hasConceptScore W2088965274C121332964 @default.
- W2088965274 hasConceptScore W2088965274C147789679 @default.
- W2088965274 hasConceptScore W2088965274C170961132 @default.
- W2088965274 hasConceptScore W2088965274C178790620 @default.
- W2088965274 hasConceptScore W2088965274C184651966 @default.
- W2088965274 hasConceptScore W2088965274C185592680 @default.
- W2088965274 hasConceptScore W2088965274C199360897 @default.
- W2088965274 hasConceptScore W2088965274C41008148 @default.
- W2088965274 hasConceptScore W2088965274C64452783 @default.
- W2088965274 hasConceptScore W2088965274C85084404 @default.
- W2088965274 hasConceptScore W2088965274C96618451 @default.
- W2088965274 hasConceptScore W2088965274C97355855 @default.
- W2088965274 hasLocation W20889652741 @default.
- W2088965274 hasOpenAccess W2088965274 @default.
- W2088965274 hasPrimaryLocation W20889652741 @default.
- W2088965274 hasRelatedWork W2000188251 @default.
- W2088965274 hasRelatedWork W2005789835 @default.
- W2088965274 hasRelatedWork W2015772873 @default.
- W2088965274 hasRelatedWork W2016336878 @default.
- W2088965274 hasRelatedWork W2044355419 @default.
- W2088965274 hasRelatedWork W2056313602 @default.
- W2088965274 hasRelatedWork W2088965274 @default.
- W2088965274 hasRelatedWork W2765611677 @default.
- W2088965274 hasRelatedWork W4383426414 @default.
- W2088965274 hasRelatedWork W1995747399 @default.
- W2088965274 hasVolume "92" @default.
- W2088965274 isParatext "false" @default.
- W2088965274 isRetracted "false" @default.
- W2088965274 magId "2088965274" @default.
- W2088965274 workType "article" @default.