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• W2088966907 endingPage "204" @default.
• W2088966907 startingPage "193" @default.
• W2088966907 abstract "The synthesis and characterization of Ru(H)2(ortho-OC6H4E)L2 (L = PiPr3, E = NH, O) show these to be dihydrides with a nonoctahedral structure. The former compound reacts with H2 to give Ru(H)3(OC6H4NH2)L2, which has the ability to hydrogenate tBuHCCH2. Osmium analogs are available from Os(H)3ClL2, and the mono-N-methyl example Os(H)2[N(Me)C6H4NH]L2 shows inequivalent hydrides by 1H NMR at 20 °C. It exchanges with D2 faster into the NH site than into the OsH sites. Triflic acid protonates Os(H)2[N(Me)C6H4NH]L2 at the metal to give a trihydride. Catechol protonates Os(H)2[N(Me)C6H4NH]L2 to displace the ortho-diamine to give Os(H)2(OC6H4O)L2. The collective evidence is consistent with a dianionic, not a quinoid oxidation state for the chelate ligands and a d4, six-coordinate potential energy surface, often with low barriers between alternative non-octahedral structures." @default.
• W2088966907 created "2016-06-24" @default.
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• W2088966907 date "2005-01-01" @default.
• W2088966907 modified "2023-09-30" @default.
• W2088966907 title "New d⁴dihydrides of Ru(<scp>iv</scp>) and Os(<scp>iv</scp>) with π-donor ligands: M(H)₂(chelate)(PⁱPr₃)₂with chelate = ortho-XYC₆H₄with X, Y = O, NR; R = H or CH₃" @default.
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• W2088966907 doi "https://doi.org/10.1039/b411487f" @default.
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