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- W2089004919 abstract "The temperature dependence of Mössbauer parameters (relatively recoil-free fraction, center shift, and quadrupole splitting) for Fe57 in the NiFe2O4 precipitation process from a silicate glass was measured to clarify vibrational properties of Fe3+ ions in the quenched glass (amorphous state) and heat treated specimens (crystalline state) in the temperature range 290–625 K. It was found that the Debye temperature of Fe3+ ions in the quenched glass is smaller than those in the heat treated specimens. It was also found that the vibrational property of Fe3+ ions in the quenched glass can be described by the single Debye model over the entire temperature range. However, anomalies in the temperature dependence of the relatively recoil-free fraction and the correlation between the relatively recoil-free fraction and center shift at high temperatures were observed in the heat treated specimens, and they were related to the presence of anharmonicity in vibrations of Fe3+ ions." @default.
- W2089004919 created "2016-06-24" @default.
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- W2089004919 date "1980-11-01" @default.
- W2089004919 modified "2023-09-27" @default.
- W2089004919 title "Temperature dependence of Mössbauer parameters for Fe57 in NiFe2O4 precipitation process from silicate glass" @default.
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- W2089004919 doi "https://doi.org/10.1063/1.327510" @default.
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