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- W2089045110 endingPage "4891" @default.
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- W2089045110 abstract "Fluorenone derivatives were generated from aryl-substituted propiolates via a cobalt-catalyzed Diels-Alder reaction/DDQ-oxidation and Friedel-Crafts-type cyclization. Several functional groups are tolerated, and good to excellent overall yields (up to 89%) could be achieved. For the synthesis of anthraquinone derivatives, aroyl-substituted propiolates were applied in a zinc iodide catalyzed Diels-Alder reaction with 1,3-dienes. The subsequent DDQ oxidation and Friedel-Crafts-type cyclization led to symmetrical as well as some unsymmetrical anthraquinones in good to excellent yields of up to 87% over the three-step reaction sequence." @default.
- W2089045110 created "2016-06-24" @default.
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- W2089045110 date "2013-09-06" @default.
- W2089045110 modified "2023-09-23" @default.
- W2089045110 title "Synthesis of Fluorenone and Anthraquinone Derivatives from Aryl- and Aroyl-Substituted Propiolates" @default.
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- W2089045110 doi "https://doi.org/10.1021/ol4023276" @default.
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