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• W2089134356 abstract "The alternating cytosine-guanine oligodeoxyribonucleotides (dCdG)n, (dGdC)n, (dCdG)ndC (n = 3,4), (dGdC)7 and dG(dCdG)3 have been studied by UV and CD spectroscopy at different temperatures and NaCl concentrations. The analysis of the melting data, assuming an all-or-none model, reveals that in the B-conformation the 5'G/C3' stacking interactions are enthalpically favoured with respect to the 5'C/G3' one. The CD investigation of the B-Z equilibrium shows that the Z-conformation is enthalpically stabilized, while the B-conformation is entropically favoured, in the range of NaCl concentration considered (1 to 5 M). The kinetic data for the B-Z transformation, obtained with a salt-jump technique for the hexamer (dCdG)3, support a mechanism by which the Watson-Crick hydrogen bonds are broken before the bases flip over separately and eventually stack, reforming the H-bonds, in the new helix." @default.
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• W2089134356 date "1987-02-01" @default.
• W2089134356 modified "2023-09-24" @default.
• W2089134356 title "dC-dG Alternating Oligonucleotides: Thermodynamic and Kinetic Aspects of the B-Z Transformation" @default.
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• W2089134356 doi "https://doi.org/10.1080/07391102.1987.10507666" @default.
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