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• W2089159137 abstract "New experimental and theoretical work has led to a re-evaluation of the Jahn-Teller effect in ReF6. Low temperature neat and mixed crystal Raman and absorption spectra have been taken. The theory applicable to two Jahn-Teller active vibrations and to a Jahn-Teller molecule in a low symmetry crystalline field is discussed. The main conclusions of the study are that (1) the standard linear Jahn-Teller treatment of vibronically active modes as independent motions characterized by a given vibronic angular momentum is in general inadequate ; (2) Renner-Teller (quadratic) or higher-order vibronic coupling terms are important ; (3) crystal-field splitting of the vibronic levels is not observed ; and (4) vibrational exciton band widths of the Jahn-Teller active vibrations are substantially reduced." @default.
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• W2089159137 date "1977-10-01" @default.
• W2089159137 modified "2023-09-27" @default.
• W2089159137 title "On the Jahn-Teller effect in ReF₆" @default.
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• W2089159137 doi "https://doi.org/10.1080/00268977700102301" @default.
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