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- W2089165150 abstract "Two new one-dimension copper(II) coordination polymers [CuL2(NCS)2]n (1) and [CuL2(NO3)2]n (2) (L = (C5H4N)C(CH3)N–N(CH3)C(C5H4N)) have been synthesized and characterized by IR, elemental analysis, TG technique and X-ray crystallography. Each Cu(II) atom has a distorted octahedral N6 (1) or N4O2 (2) environment with four pyridyl N atoms from four ligands and two N atoms from two NCS− anions for polymer 1 or two O atoms from two NO3− anions for polymer 2, respectively. A pair of bis-monodentate bridging ligands links two Cu(II) centers to form one dimension chain structure containing bimetallic 22-membered macrometallacyclic rings. 1D chain is held together with its neighboring ones via C–H⋯S hydrogen bonds for 1 and C–H⋯O hydrogen bonds, C–H⋯π interactions for 2 to form a 3D supramolecular structure, respectively. The luminescent properties of the polymers 1 and 2 were investigated in the solid state at room temperature." @default.
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- W2089165150 date "2011-12-01" @default.
- W2089165150 modified "2023-09-27" @default.
- W2089165150 title "Two one-dimension copper(II) coordination polymers based on imine-based bidentate Schiff-base ligand: Synthesis, crystal structure and luminescent properties" @default.
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- W2089165150 doi "https://doi.org/10.1016/j.saa.2011.08.073" @default.
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