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- W2089165860 abstract "Solvation characteristics of a ketocyanine dye have been studied in completely miscible ternary solvent mixtures, namely, methanol + acetone + water and methanol + acetone + benzene, by monitoring the solvatochromic absorption band of the dye. The maximum energy of absorption (E) of the solute in a ternary solvent mixture differs significantly from the mole fraction average of the E values in the component solvents. Results in the corresponding binary solvent mixtures also show a deviation of the E value from the mole fraction averaged E values. The results have been explained in terms of preferential solvation using a two phase model of solvation. The excess or deficit over the bulk composition of a solvent component in the vicinity of the solute molecule in a ternary solvent mixture has been estimated using the knowledge of solvation in the corresponding binary mixtures." @default.
- W2089165860 created "2016-06-24" @default.
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- W2089165860 date "2008-01-29" @default.
- W2089165860 modified "2023-09-26" @default.
- W2089165860 title "UV-Visible Spectroscopic Study of Solvation in Ternary Solvent Mixtures: Ketocyanine Dye in Methanol + Acetone + Water and Methanol + Acetone + Benzene" @default.
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- W2089165860 doi "https://doi.org/10.1021/jp709819n" @default.
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