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- W2089217777 endingPage "762" @default.
- W2089217777 startingPage "759" @default.
- W2089217777 abstract "Two electrons in two weakly coupled orbitals give rise to two states (diradical) with electrons residing in separate orbitals and two states (zwitterionic) with both electrons paired in one orbital or the other. This two-electron, two-orbital state manifold has eluded experimental confirmation because the zwitterionic states have been difficult to locate. Two-photon excitation of fluorescence from Mo2CI4(PMe3)4 (D2d) has been measured with linearly and circularly polarized light. From the polarization ratio and the energy of the observed transition, the 21A1 (δ*δ*) excited state has been located and characterized. In conjunction with the one-photon allowed 1B2 (δδ*) excited state, the zwitterionic state manifold for the quadruply bonded metal-metal class of compounds is thus established." @default.
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- W2089217777 date "1994-08-05" @default.
- W2089217777 modified "2023-09-23" @default.
- W2089217777 title "Direct Spectroscopic Detection of a Zwitterionic Excited State" @default.
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- W2089217777 doi "https://doi.org/10.1126/science.265.5173.759" @default.
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