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- W2089224710 abstract "The rotation-inversion spectrum of $^{14}mathrm{NT}_{3}$ in the ground vibrational state has been measured with high-resolution microwave techniques in the frequency range of 210-633 GHz. Components of the $J=0ensuremath{rightarrow}1, 1ensuremath{rightarrow}2, mathrm{and} 2ensuremath{rightarrow}3$ transitions were observed. Analysis of the results yielded the following rotational constants: ${B}_{0}=105565.373ifmmodepmelsetextpmfi{}0.034$ MHz, ${D}_{J}=2.5981ifmmodepmelsetextpmfi{}0.0024$ MHz, and ${D}_{JK}=ensuremath{-}4.472ifmmodepmelsetextpmfi{}0.006$ MHz, with the $^{14}mathrm{N}$ nuclear quadrupole coupling $eqQ=ensuremath{-}4.170ifmmodepmelsetextpmfi{}0.049$ MHz. The inversion frequency, corrected for rotational distortion, was found to be 305.89 ifmmodepmelsetextpmfi{} 0.11 MHz. Molecular substitution structures obtained were bond length 1.0132 AA{}A and bond angle 107ifmmode^circelsetextdegreefi{} 13' for the combination $^{14}mathrm{NH}_{3}$: $^{15}mathrm{NH}_{3}$, $^{14}mathrm{NT}_{3}$; bond length 1.0128 AA{}A and bond angle 107ifmmode^circelsetextdegreefi{} 2' for the combination $^{14}mathrm{ND}_{3}$: $^{15}mathrm{ND}_{3}$, $^{14}mathrm{NT}_{3}$." @default.
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- W2089224710 title "Microwave rotation-inversion spectrum of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>NT</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>" @default.
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- W2089224710 doi "https://doi.org/10.1103/physreva.9.12" @default.
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