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- W2089236955 abstract "(2,2,2-Trifluorethyliden)schwefeltetrafluorid, CF3CH=SF4 (9a), entsteht in einer Vielstufensynthese aus HCC-OR (1a, b) und SF5Cl. In der letzten Stufe wird es zusammen mit dem Isomeren F2C=CH-SF5 (10a) durch LiF-Eliminierung von LiCHCF3–SF5 (8a) gebildet. Gleichermaßen entstehen aus CH3CC-OR (1c, d) und SF5Cl in mehreren Stufen CF3C(CH3)=SF4 (9c) und F2C=C(CH3)–SF5 (10c). Die beiden neuen Alkylidenschwefeltetrafluoride 9a, c sind der dritte und vierte Vertreter dieser Verbindungsklasse; sie sind besonders stabil. Die Struktur der beiden Verbindungen ist analog zu H2C=SF4 und CH3CH=SF4. New Alkylidenesulfur Tetrafluorides: CF3CH=SF4 and CF3C(CH3)=SF4 (2,2,2-Trifluoroethylidene)sulfur tetrafluoride, CF3CH=SF4 (9a), is made from HCC-OR (1a, b) and SF5Cl in a multistep preparation. In the last step 9a is formed along with the isomer F2C=CH-SF5 (10a) by LiF elimination from LiCHCF3–SF5 (8a). CF3C(CH3)=SF4 (9c) and F2C=C(CH3)–SF5 (10c) are formed likewise in several steps from CH3CC-OR (1c, d) and SF5Cl. The new alkylidenesulfur tetrafluorides 9a, c are the third and forth members of this class of compounds, and they are especially stable. Their structure is analogous to the structures of H2C=SF4 and CH3CH=SF4." @default.
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- W2089236955 date "1984-11-01" @default.
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- W2089236955 title "Neue Alkylidenschwefeltetrafluoride: CF <sub>3</sub> CH=SF <sub>4</sub> und CF <sub>3</sub> C(CH <sub>3</sub> )=SF <sub>4</sub>" @default.
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- W2089236955 doi "https://doi.org/10.1002/cber.19841171110" @default.
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