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- W2089253318 abstract "Treatment of β,β-disubstituted enamines with potassium permanganste supported on neutral alumina leads to a mild and selective oxidative cleavage reaction which produces ketones and formamides. The ketones can be isolated in high yield and purity by a simple workup procedure. The oxidizing agent is selective and preferentially oxidizes an enamine carbon-carbon double bond in the presence of a distal carbon-carbon double bond. Other functional groups unaffected by this reagent include nitriles, secondary alcohols, and alkynes allowing a wide range of potentially selective oxidations." @default.
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- W2089253318 date "1997-02-01" @default.
- W2089253318 modified "2023-09-26" @default.
- W2089253318 title "Enamine oxidations. 2. Selective oxidative cleavage of β,β - disubstituted enamines using alumina supported permanganate. Synthesis of one-carbon dehomologated carbonyl compounds from enamines" @default.
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- W2089253318 doi "https://doi.org/10.1016/s0040-4039(96)02504-x" @default.
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