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- W2089282817 abstract "Abstract The heat capacity of a sample of Na3UO4 was measured from 5 to 350 K with an adiabatic calorimeter. The result near 30 K, where UO2 has a sharp λ-type anomaly, indicated the presence of (0.68±0.06) mass per cent UO2, and a correction for this amount of UO2 was applied to the experimental heat capacities. The following values were obtained for pure Na3UO4: heat capacity at constant pressure: Cp(298.15 K)=(173.0±0.4) J K−1 mol−1; entropy So(298.15 K)=(198.2±0.4) J K−1 mol−1; enthalpy increment: {Ho(298.15 K)−Ho(0)}=(31109±62) J mol−1; Gibbs energy divided by temperature value for the entropy of Na3UO4 with the entropies of Na, U, and O2 and with the enthalpy of formation of Na3UO4 reported by O'Hare, Shinn, Mrazek, and Martin yields −(448.0±1.0) kcalth mol−1 for the Gibbs energy of formation ΔGfo(Na3UO4, c, 298.15 K)." @default.
- W2089282817 created "2016-06-24" @default.
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- W2089282817 date "1972-05-01" @default.
- W2089282817 modified "2023-09-27" @default.
- W2089282817 title "Thermodynamic investigation of trisodium uranium (V) oxide (Na3UO4) II. Heat capacity, entropy, and enthalpy increment from 5 to 350 K. Gibbs energy of formation at 298.15 K" @default.
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- W2089282817 doi "https://doi.org/10.1016/0021-9614(72)90024-9" @default.
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