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- W2089304050 abstract "Phase transitions in the systems VHx and VDx for 0.443 ⩽ x ⩽ 0.815 were determined using a resistiometric technique supplemented by differential scanning calorimetry. The use of inflection points in the resistivity versus temperature heating curve to determine the phase boundaries was found to give results consistent with those obtained using differential scanning calorimetry. Comparisons with recently published VHx and VDx phase diagrams give generally good agreement and verify the unusually large isotopic differences observed by other techniques. No evidence is found for the η phase or for the β1 + β2 mixed phase in the VHx system. The concentration dependence of the resistivity in the a phase shows a small isotope effect. For both VHx and VDx the variation with x indicates the existence of local regions of β phase the extent of which are of the order of 25Å or more. In the β phase of VHx the x dependence of the resistivity indicates partial ordering of hydrogen in the β1 region and complete disorder in the β2 region." @default.
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- W2089304050 date "1980-11-01" @default.
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- W2089304050 title "Resistiometric determination of phase transformations in VHx and VDx" @default.
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- W2089304050 doi "https://doi.org/10.1016/0022-5088(80)90118-6" @default.
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