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• W2089322790 startingPage "5167" @default.
• W2089322790 abstract "Abstract The volatiles released by several strains of Trichoderma fungi were collected using a closed‐loop stripping apparatus and analysed by GC–MS. Most of the investigated strains released the two structurally related spirocyclic sesquiterpenoids trichoacorenol, previously identified in Trichoderma koningii (Huang et al., 1995), and acorenone. A new enantioselective synthesis of the enantiomer of the natural spirocyclic sesquiterpene acorenone and the first enantioselective synthesis of the related compound ent ‐trichoacorenol have been completed by a chiral‐pool approach starting from (+)‐( R )‐pulegone using ring‐closing metathesis as the key step. The absolute configuration of natural trichoacorenol from Trichoderma harzianum sp. 714 has been assigned by chiral GC–MS analysis and is the same as that in T. koningii ." @default.
• W2089322790 created "2016-06-24" @default.
• W2089322790 creator A5002676236 @default.
• W2089322790 creator A5028993446 @default.
• W2089322790 date "2011-07-20" @default.
• W2089322790 modified "2023-09-25" @default.
• W2089322790 title "Enantioselective Synthesis of the Unnatural Enantiomers of the Fungal Sesquiterpenoids Acorenone and Trichoacorenol" @default.
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• W2089322790 doi "https://doi.org/10.1002/ejoc.201100688" @default.
• W2089322790 hasPublicationYear "2011" @default.
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