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- W2089463764 abstract "The valence band offsets of the common-anion CdTe–HgTe, CdTe–ZnTe, ZnTe–HgTe, and GaAs–AlAs semiconductor pairs are calculated from the core level energies. The good agreement obtained with experiment for lattice-matched systems and a simple electrostatic model analysis suggest interface dipoles to have only a small effect. Furthermore, the microscopic origin of the failure of the common-anion rule in lattice-matched systems is identified: it is found that participation of cation d orbitals (neglected by tight-binding and pseudopotential approaches alike) in the valence band maxima is responsible for much of the band offset in these systems." @default.
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- W2089463764 date "1987-07-01" @default.
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- W2089463764 title "Calculation of the valence band offsets of common-anion semiconductor heterojunctions from core levels: The role of cation <i>d</i> orbitals" @default.
- W2089463764 doi "https://doi.org/10.1116/1.583720" @default.
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