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- W2089488281 abstract "In addition to the traditional Krätschmer–Huffman graphite arc-discharge method, a combustion method has been developed to synthesize fullerenes that defy the isolated pentagon rule (IPR). The C3v-symmetric #1911C64H4, as well as other non-IPR fullerenes such as the possible non-IPR C60 isomer, have been synthesized as fullerene hydrides in a low-pressure benzene/oxygen diffusion flame. The non-IPR structure of the chromatographically isolated C64 species was unambiguously identified by its HPLC retention time, UV absorption and mass spectrum by comparison with the reference material C3v-#1911C64H4. The synthesis, isolation and identification of C3v-#1911C64H4, as described in this work, show that this combustion method is successful, is energy efficient and is a promising candidate for the macroscopic synthesis of non-IPR fullerenes." @default.
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- W2089488281 date "2010-05-01" @default.
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- W2089488281 title "Synthesis of C3v-#1911C64H4 using a low-pressure benzene/oxygen diffusion flame: Another pathway toward non-IPR fullerenes" @default.
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- W2089488281 doi "https://doi.org/10.1016/j.combustflame.2009.12.004" @default.
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