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• W2089492868 abstract "Facile nitrite reduction was achieved using [FeII(HCTPPH)NO] as the starting compound to react with NaNO2. Stoichiometric studies allow the isolation of both {Fe(NO)}6 and {Fe(NO)}7 nitrosyl complexes and provide insight into the proton and electron transfer processes during the nitrite reduction. Treating [Fe(CTPP)NO] with acid or oxidizing [Fe(HCTPP)NO] with AgClO4 yields intermediate [Fe(HCTPP)NO]+. The conversion cycles starting from {Fe(NO)}6 [Fe(CTPP)NO] to {Fe(NO)}6 [Fe(HCTPP)NO][ClO4] then to {Fe(NO)}7 [Fe(HCTPP)NO] and vice versa were constructed." @default.
• W2089492868 created "2016-06-24" @default.
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• W2089492868 date "2009-05-21" @default.
• W2089492868 modified "2023-10-16" @default.
• W2089492868 title "Facile Nitrite Reduction and Conversion Cycle of {Fe(NO)}6/7 Species: Chemistry of Iron N-Confused Porphyrin Complexes via Protonation/Deprotonation" @default.
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• W2089492868 doi "https://doi.org/10.1021/ja901796j" @default.
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