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- W2089495344 abstract "The compounds tert-butylarsenium(III) tri-μ-chlorido-bis[trichloridotitanium(IV)], (C4H12As)[Ti2Cl9] or [tBuAsH3][Ti2(μ-Cl)3Cl6], (II), and bis[bromidotriphenylarsenium(V)] di-μ-bromido-μ-oxido-bis[tribromidotitanium(IV)], (C18H15AsBr)2[Ti2Br8O] or [Ph3AsBr]2[Ti2(μ-O)(μ-Br)2Br6], (III), were obtained unexpectedly from the reaction of simple arsane ligands with TiIV halides, with (II) lying on a mirror plane in the unit cell of the space group Pbcm. Both compounds contain a completely novel ion, with [tBuAsH3]+ constituting the first structurally characterized example of a primary arsenium cation. The oxide-bridged titanium-containing [Ti2(μ-O)(μ-Br)2Br6]2− dianion in (III) is also novel, while the bromidotriphenylarsenium(V) cation is structurally characterized for only the second time." @default.
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- W2089495344 date "2011-03-04" @default.
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- W2089495344 title "Novel ion pairs obtained from the reaction of titanium(IV) halides with simple arsane ligands" @default.
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- W2089495344 doi "https://doi.org/10.1107/s0108270111006639" @default.
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