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- W2089605779 abstract "Abstract A neutron diffraction study has been carried out on a 3.25 modal solution of NaClO 4 in heavy water, in which the first-order difference method of isotopic substitution was applied to chlorine atoms of the ClO 4 − ion. The results show that (a) the intramolecular separation of Cl-O is 1.43 ± 0.02 A in good agreement with X-ray diffraction results from single-crystal studies. (b) there are between four and five nearest-neighbour deuterium atoms in the range 2.4 ⩽ r ⩽ 3.2 A. and (c) the ClO 4 − -water coordination is less well defined than that for Cl − -water, but similar to that for the NO 3 − -water structure." @default.
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- W2089605779 date "1985-12-01" @default.
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- W2089605779 title "The structure around the perchlorate ion in concentrated aqueous solutions" @default.
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- W2089605779 doi "https://doi.org/10.1016/0009-2614(85)87249-3" @default.
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