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- W2089654740 abstract "The reaction of molybdenum and chromium hexacarbonyls with formamidines yields the tetrakis(formamidinato)dimolybdenum and dichromium complexes. In the case of molybdenum we were able to set up a reaction scheme for the formation of these complexes. An interesting feature of the chemistry of these complexes is the reaction with Mo(CO)6 or Cr(CO)6 to yield novel complexes in which an “M(CO)3” species is bound to one of the aromatic groups. Their physical and chemical properties are discussed. The reaction of W(CO)6 with formamidine did not produce a complex analogous to that obtained with Mo(CO)6 or Cr(CO)6 but, instead, a deep purple coloured complex." @default.
- W2089654740 created "2016-06-24" @default.
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- W2089654740 date "1977-07-01" @default.
- W2089654740 modified "2023-09-27" @default.
- W2089654740 title "Reactions of group vib hexacarbonyls with formamidines" @default.
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- W2089654740 doi "https://doi.org/10.1016/0022-5088(77)90143-6" @default.
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