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• W2089662690 abstract "The polymerization strategy plays a vital role in the preparation of functional microspheres. In this work, fluorescent poly (styrene-co-glycidyl methacrylate) (PSt-GMA) microspheres were synthesized via one-stage and two-stage dispersion polymerization with 4-Bis(5-phenyl-1,3-oxazol-2-yl)benzene (POPOP) as fluorescence agent. SEM and DLS were adopted to characterize the properties of prepared microspheres. The UV-vis and fluorescence spectroscopy were used to analyze the mechanisms of two-stage dispersion polymerization. The experimental results showed that the size distribution and fluorescence intensity of prepared microspheres could be improved by two-stage dispersion polymerization compared to one-stage dispersion polymerization. In addition, according to UV-vis, the interactions between POPOP and Poly (N-vinyl pyrrolidone) (PVP) as well as POPOP and Glycidyl methacrylate (GMA) could affect the particle size and its distribution. UV-vis and fluorescence spectra implied that the POPOP existed outside of the particle's core via two-stage strategy. The monomer conversion of styrene was similar at the beginning of reaction; however, the monomer conversion of styrene by two-stage strategy was higher than that of by one-stage strategy. In a word, two-stage dispersion polymerization could prepare fluorescent microspheres with the monodispersion micrometer-size and high quality. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41927." @default.
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• W2089662690 date "2015-01-21" @default.
• W2089662690 modified "2023-09-27" @default.
• W2089662690 title "Different dispersion polymerization strategies influence the quality of fluorescent poly (St-co-GMA) microspheres" @default.
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• W2089662690 doi "https://doi.org/10.1002/app.41927" @default.
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