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- W2089699052 abstract "We recently reported the first pump−probe measurements on the hydrated electron with sufficient time resolution (∼35 fs) to directly observe the initial processes in the solvation dynamics of this key prototype for condensed-phase dynamics [Silva, C.; Walhout, P. K.; Yokoyama, K.; Barbara, P. F. Phys. Rev. Lett. 1998, 80, 1086]. An unprecedented relaxation process for the hydrated electron was observed that occurs on the 35−80 fs time scale and exhibits a solvent isotope effect (τ(D2O)/τ(H2O) ∼ 1.4). The new process was assigned to inertial/librational motion of the water surrounding the excess electron. The present paper reports a more extensive study of the ∼35 fs resolved dynamics of the hydrated electron in H2O and D2O at more probe wavelengths and as a function of pump-pulse intensity. The results are in agreement with the preliminary report and support the importance of librational water motion in the relaxation dynamics of the hydrated electron. New high excitation pulse intensity measurements reveal evidence of a high-intensity, two-photon channel involving ejection of the hydrated electron from its initial site to a different site in the solvent." @default.
- W2089699052 created "2016-06-24" @default.
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- W2089699052 date "1998-08-01" @default.
- W2089699052 modified "2023-10-17" @default.
- W2089699052 title "Detailed Investigation of the Femtosecond Pump−Probe Spectroscopy of the Hydrated Electron" @default.
- W2089699052 cites W146320344 @default.
- W2089699052 cites W1963671982 @default.
- W2089699052 cites W1965484091 @default.
- W2089699052 cites W1966064521 @default.
- W2089699052 cites W1968559446 @default.
- W2089699052 cites W1968760701 @default.
- W2089699052 cites W1968925848 @default.
- W2089699052 cites W1971593721 @default.
- W2089699052 cites W1973747581 @default.
- W2089699052 cites W1981974472 @default.
- W2089699052 cites W1982163348 @default.
- W2089699052 cites W1983379895 @default.
- W2089699052 cites W1987921149 @default.
- W2089699052 cites W1988797087 @default.
- W2089699052 cites W1992147585 @default.
- W2089699052 cites W1996441837 @default.
- W2089699052 cites W1996613273 @default.
- W2089699052 cites W2000038359 @default.
- W2089699052 cites W2000521482 @default.
- W2089699052 cites W2002836236 @default.
- W2089699052 cites W2007700073 @default.
- W2089699052 cites W2010772149 @default.
- W2089699052 cites W2012235895 @default.
- W2089699052 cites W2013092541 @default.
- W2089699052 cites W2013567882 @default.
- W2089699052 cites W2014063669 @default.
- W2089699052 cites W2014243239 @default.
- W2089699052 cites W2019172414 @default.
- W2089699052 cites W2019955938 @default.
- W2089699052 cites W2021973309 @default.
- W2089699052 cites W2022243104 @default.
- W2089699052 cites W2023194376 @default.
- W2089699052 cites W2024456163 @default.
- W2089699052 cites W2024777521 @default.
- W2089699052 cites W2026270682 @default.
- W2089699052 cites W2032228544 @default.
- W2089699052 cites W2036189046 @default.
- W2089699052 cites W2038029283 @default.
- W2089699052 cites W2039929450 @default.
- W2089699052 cites W2040685329 @default.
- W2089699052 cites W2042701373 @default.
- W2089699052 cites W2042849936 @default.
- W2089699052 cites W2043979193 @default.
- W2089699052 cites W2046092966 @default.
- W2089699052 cites W2046342343 @default.
- W2089699052 cites W2046690056 @default.
- W2089699052 cites W2050957697 @default.
- W2089699052 cites W2054947925 @default.
- W2089699052 cites W2055442639 @default.
- W2089699052 cites W2056873954 @default.
- W2089699052 cites W2061653486 @default.
- W2089699052 cites W2064657560 @default.
- W2089699052 cites W2065298212 @default.
- W2089699052 cites W2065709195 @default.
- W2089699052 cites W2066954224 @default.
- W2089699052 cites W2067001445 @default.
- W2089699052 cites W2068267942 @default.
- W2089699052 cites W2069922559 @default.
- W2089699052 cites W2071012557 @default.
- W2089699052 cites W2074065589 @default.
- W2089699052 cites W2075586555 @default.
- W2089699052 cites W2076611240 @default.
- W2089699052 cites W2076634268 @default.
- W2089699052 cites W2077444299 @default.
- W2089699052 cites W2079551157 @default.
- W2089699052 cites W2081604665 @default.
- W2089699052 cites W2082496187 @default.
- W2089699052 cites W2085831702 @default.
- W2089699052 cites W2087937597 @default.
- W2089699052 cites W2095159220 @default.
- W2089699052 cites W2098680229 @default.
- W2089699052 cites W2106062711 @default.
- W2089699052 cites W2111518657 @default.
- W2089699052 cites W2125252982 @default.
- W2089699052 cites W2128758547 @default.
- W2089699052 cites W2137148785 @default.
- W2089699052 doi "https://doi.org/10.1021/jp981809p" @default.
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