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- W2089774321 abstract "The products of silaneO2 mixture explosions vary with mixture composition. For O2-rich mixtures (>70% O2), the products are H2O and SiO2. As the mixtures become richer in silane, H2 replaces H2O as a final product. For very SiH4-rich mixtures (>70% SiH4), the products are H2, SiOx, and Si. The fact that silane is totally consumed in silane-rich mixtures (70–90% silane) demonstrates that solid particle formation (SiO2, SiO, and Si) occurs very rapidly and that the accompanying heat release is essential to drive the reactions to completion. It is also clear that the explosion of a silane-rich mixture is primarily a thermal explosion of silane. Effects due to problems associated with upper pressure limit measurements and mechanistic aspects of the SiH4O2 explosion reaction are discussed." @default.
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- W2089774321 date "1987-04-01" @default.
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- W2089774321 title "Stoichiometry and possible mechanism of SiH4O2 explosions" @default.
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- W2089774321 doi "https://doi.org/10.1016/0010-2180(87)90064-2" @default.
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