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- W2089834406 abstract "Abstract The 15 N‐NMR spectra of cis ‐ and trans ‐2,3‐dialkyl‐substituted triaziridines are reported. The assignment of the 15 N‐NMR resonances is described, and the chemical‐shift and coupling data are compared with those of aziridines and diaziridines. The 1 J (N,H) coupling constants allow one to deduce the relative configuration of the involved N‐atom. In CDCl 3 , a 1 J (N,H) value of 58.1 ± 0.5 Hz is assigned to an NH bond cis to two lone‐pairs of electrons at neighboring N‐atoms, i.e. to the cis , trans ‐triaziridines The first stereodescriptor denotes the relative configuration of the two equal alkyl substituents, the second the relative configuration of one alkyl substituent and the H‐atom. , and a value of 51.7 ± 0.5 Hz is assigned to a NH bond cis to only one lone‐pair of electrons, i.e. to trans , cis ‐triaziridines ." @default.
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- W2089834406 date "1986-02-05" @default.
- W2089834406 modified "2023-09-29" @default.
- W2089834406 title "15N-NMR Spectroscopic Characterization of Triaziridines" @default.
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- W2089834406 doi "https://doi.org/10.1002/hlca.19860690116" @default.
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